Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate

In the mononuclear title compound, [Tb(C(13)H(9)OS(3))(3)(C(4)H(8)O)(3)]·C(4)H(8)O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octa­hedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0...

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Detalles Bibliográficos
Autores principales: Veith, Michael, Belot, Celine, Huch, Volker
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238632/
https://www.ncbi.nlm.nih.gov/pubmed/22199523
http://dx.doi.org/10.1107/S160053681104623X
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author Veith, Michael
Belot, Celine
Huch, Volker
author_facet Veith, Michael
Belot, Celine
Huch, Volker
author_sort Veith, Michael
collection PubMed
description In the mononuclear title compound, [Tb(C(13)H(9)OS(3))(3)(C(4)H(8)O)(3)]·C(4)H(8)O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octa­hedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis.
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spelling pubmed-32386322011-12-23 Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate Veith, Michael Belot, Celine Huch, Volker Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title compound, [Tb(C(13)H(9)OS(3))(3)(C(4)H(8)O)(3)]·C(4)H(8)O, the lanthanide cation is located on a threefold rotation axis and is surrounded by electron-rich ligands in an approximately octa­hedral geometry. One of the thienyl groups and the bound THF are disordered with 0.5:0.5 occupancy. The free THF is disordered around the threefold axis. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238632/ /pubmed/22199523 http://dx.doi.org/10.1107/S160053681104623X Text en © Veith et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Veith, Michael
Belot, Celine
Huch, Volker
Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate
title Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate
title_full Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate
title_fullStr Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate
title_full_unstemmed Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate
title_short Tris(tetra­hydro­furan-κO)tris­[tris­(thio­phen-2-yl)methano­lato-κO]terbium(III) tetra­hydro­furan monosolvate
title_sort tris(tetra­hydro­furan-κo)tris­[tris­(thio­phen-2-yl)methano­lato-κo]terbium(iii) tetra­hydro­furan monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238632/
https://www.ncbi.nlm.nih.gov/pubmed/22199523
http://dx.doi.org/10.1107/S160053681104623X
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AT huchvolker tristetrahydrofurankotristristhiophen2ylmethanolatokoterbiumiiitetrahydrofuranmonosolvate

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