[1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate

The title compound, [Cu(C(12)H(8)N(2))(C(27)H(26)P(2))]ClO(4), crystallizes with two Cu(I) complex cations and two perchlorate anions in the asymmetric unit. Each Cu(I) cation is four-coordinated by two P atoms of a 1,3-bis­(diphenyl­phosphan­yl)propane mol­ecule and two N atoms of a 1,10-phenanthro...

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Autores principales: Xiao, Ye-Lan, Zhou, Li-Li, Gao, Sen, Jin, Qiong-Hua, Zhang, Cun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238633/
https://www.ncbi.nlm.nih.gov/pubmed/22199524
http://dx.doi.org/10.1107/S160053681104606X
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author Xiao, Ye-Lan
Zhou, Li-Li
Gao, Sen
Jin, Qiong-Hua
Zhang, Cun-Lin
author_facet Xiao, Ye-Lan
Zhou, Li-Li
Gao, Sen
Jin, Qiong-Hua
Zhang, Cun-Lin
author_sort Xiao, Ye-Lan
collection PubMed
description The title compound, [Cu(C(12)H(8)N(2))(C(27)H(26)P(2))]ClO(4), crystallizes with two Cu(I) complex cations and two perchlorate anions in the asymmetric unit. Each Cu(I) cation is four-coordinated by two P atoms of a 1,3-bis­(diphenyl­phosphan­yl)propane mol­ecule and two N atoms of a 1,10-phenanthroline ligand, with a coordination geometry that can be considered as distorted tetra­hedral. The crystal studied was twinned with a twin ratio of 0.786 (2):0.214 (2).
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spelling pubmed-32386332011-12-23 [1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate Xiao, Ye-Lan Zhou, Li-Li Gao, Sen Jin, Qiong-Hua Zhang, Cun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(12)H(8)N(2))(C(27)H(26)P(2))]ClO(4), crystallizes with two Cu(I) complex cations and two perchlorate anions in the asymmetric unit. Each Cu(I) cation is four-coordinated by two P atoms of a 1,3-bis­(diphenyl­phosphan­yl)propane mol­ecule and two N atoms of a 1,10-phenanthroline ligand, with a coordination geometry that can be considered as distorted tetra­hedral. The crystal studied was twinned with a twin ratio of 0.786 (2):0.214 (2). International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238633/ /pubmed/22199524 http://dx.doi.org/10.1107/S160053681104606X Text en © Xiao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiao, Ye-Lan
Zhou, Li-Li
Gao, Sen
Jin, Qiong-Hua
Zhang, Cun-Lin
[1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate
title [1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate
title_full [1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate
title_fullStr [1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate
title_full_unstemmed [1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate
title_short [1,3-Bis(diphenyl­phosphan­yl)propane-κ(2) P,P′](1,10-phenanthroline-κ(2) N,N′)copper(I) perchlorate
title_sort [1,3-bis(diphenyl­phosphan­yl)propane-κ(2) p,p′](1,10-phenanthroline-κ(2) n,n′)copper(i) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238633/
https://www.ncbi.nlm.nih.gov/pubmed/22199524
http://dx.doi.org/10.1107/S160053681104606X
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