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Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)]
In the title compound, [KYb(C(2)O(4))(2)(H(2)O)(4)](n), the Yb(III) ion lies on a site of [Image: see text] symmetry in a dodecahedral environment defined by eight O atoms from four oxalate ligands. The K atom lies on a different [Image: see text] axis and is coordinated by four O atoms from four o...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238636/ https://www.ncbi.nlm.nih.gov/pubmed/22199527 http://dx.doi.org/10.1107/S1600536811046022 |
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author | Zhang, Feng-Ming Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming |
author_facet | Zhang, Feng-Ming Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming |
author_sort | Zhang, Feng-Ming |
collection | PubMed |
description | In the title compound, [KYb(C(2)O(4))(2)(H(2)O)(4)](n), the Yb(III) ion lies on a site of [Image: see text] symmetry in a dodecahedral environment defined by eight O atoms from four oxalate ligands. The K atom lies on a different [Image: see text] axis and is coordinated by four O atoms from four oxalate ligands and four water O atoms. The oxalate ligand has an inversion center at the mid-point of the C—C bond. The metal ions are linked by the oxalate ligands into a three-dimensional framework. O—H⋯O hydrogen bonding is present in the crystal structure. |
format | Online Article Text |
id | pubmed-3238636 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386362011-12-23 Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] Zhang, Feng-Ming Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [KYb(C(2)O(4))(2)(H(2)O)(4)](n), the Yb(III) ion lies on a site of [Image: see text] symmetry in a dodecahedral environment defined by eight O atoms from four oxalate ligands. The K atom lies on a different [Image: see text] axis and is coordinated by four O atoms from four oxalate ligands and four water O atoms. The oxalate ligand has an inversion center at the mid-point of the C—C bond. The metal ions are linked by the oxalate ligands into a three-dimensional framework. O—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238636/ /pubmed/22199527 http://dx.doi.org/10.1107/S1600536811046022 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Feng-Ming Hou, Guang-Feng Yan, Peng-Fei Li, Guang-Ming Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] |
title | Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] |
title_full | Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] |
title_fullStr | Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] |
title_full_unstemmed | Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] |
title_short | Poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(III)] |
title_sort | poly[tetraaquadi-μ(4)-oxalato-potassiumytterbium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238636/ https://www.ncbi.nlm.nih.gov/pubmed/22199527 http://dx.doi.org/10.1107/S1600536811046022 |
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