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catena-Poly[[[(pyridine-κN)copper(II)]-μ-3-{1-[(2-amino­eth­yl)imino]­eth­yl}-6-methyl-2-oxo-2H-pyran-4-olato-κ(4) N,N,O (4):O (2)] perchlorate]

In the title compound, {[Cu(C(10)H(13)N(2)O(3))(C(5)H(5)N)]ClO(4)}(n), the Cu(II) atom has an N(3)O(2) coordination sphere. The complex contains two different ligands, viz. a pyridine mol­ecule and a Schiff base mol­ecule, resulting from the condensation of ethyl­enodiamine with dehydro­acetic acid....

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Detalles Bibliográficos
Autores principales: Ourari, Ali, Derafa, Wassila, Bouacida, Sofiane, Aggoun, Djouhra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238637/
https://www.ncbi.nlm.nih.gov/pubmed/22199528
http://dx.doi.org/10.1107/S1600536811046411
Descripción
Sumario:In the title compound, {[Cu(C(10)H(13)N(2)O(3))(C(5)H(5)N)]ClO(4)}(n), the Cu(II) atom has an N(3)O(2) coordination sphere. The complex contains two different ligands, viz. a pyridine mol­ecule and a Schiff base mol­ecule, resulting from the condensation of ethyl­enodiamine with dehydro­acetic acid. The Cu(II) atom exhibits a square-pyramidal geometry: three of the four donors of the pyramid base belong to the Schiff base ligand (an N atom from the amine group, a second N atom from the imine group and the O atom of the pyran­one residue) and the fourth donor is the pyridine N atom. The coordination around the metal ion is completed by a longer axial bond to the pyran­one O atom of an adjacent Schiff base, so forming a one-dimensional polymer. The complex has a +1 charge that is compensated by a perchlorate ion. The crystal packing, which can be described as alternating chains of cations and tetra­hedral perchlorate anions along the a axis, is stabilized by inter­molecular N—H⋯O, C—H⋯O and C—H⋯N hydrogen-bonding interactions.