Dichlorido[(4E,11E)-5,7,12,14-tetra­benzyl-7,14-dimethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-4,11-diene]cobalt(III) perchlorate

The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octa­hedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetra­dentate macrocylic ligand and two chloride ions. The N—H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with c...

Descripción completa

Detalles Bibliográficos
Autores principales: Roy, Tapashi G., Hazari, Saroj K. S., Barua, Kanak K., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238638/
https://www.ncbi.nlm.nih.gov/pubmed/22199529
http://dx.doi.org/10.1107/S1600536811046484
Descripción
Sumario:The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octa­hedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetra­dentate macrocylic ligand and two chloride ions. The N—H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C—H⋯O inter­actions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4).

Ejemplares similares