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Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate
The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N—H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with c...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238638/ https://www.ncbi.nlm.nih.gov/pubmed/22199529 http://dx.doi.org/10.1107/S1600536811046484 |
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| author | Roy, Tapashi G. Hazari, Saroj K. S. Barua, Kanak K. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Roy, Tapashi G. Hazari, Saroj K. S. Barua, Kanak K. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Roy, Tapashi G. |
| collection | PubMed |
| description | The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N—H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C—H⋯O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4). |
| format | Online Article Text |
| id | pubmed-3238638 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386382011-12-23 Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate Roy, Tapashi G. Hazari, Saroj K. S. Barua, Kanak K. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(III) atom in the title complex, [CoCl(2)(C(40)H(48)N(4))]ClO(4), is octahedrally coordinated within a trans-Cl(2)N(4) donor set provided by the tetradentate macrocylic ligand and two chloride ions. The N—H atoms, which are orientated to one side of the N(4) plane, form hydrogen bonds with chloride ions and perchlorate-O atoms. These along with C—H⋯O interactions consolidate the three-dimensional crystal structure. One of the benzene rings was disordered. This was resolved over two positions with the major component of the disorder having a site-occupancy factor of 0.672 (4). International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238638/ /pubmed/22199529 http://dx.doi.org/10.1107/S1600536811046484 Text en © Roy et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Roy, Tapashi G. Hazari, Saroj K. S. Barua, Kanak K. Ng, Seik Weng Tiekink, Edward R. T. Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate |
| title | Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate |
| title_full | Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate |
| title_fullStr | Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate |
| title_full_unstemmed | Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate |
| title_short | Dichlorido[(4E,11E)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(III) perchlorate |
| title_sort | dichlorido[(4e,11e)-5,7,12,14-tetrabenzyl-7,14-dimethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene]cobalt(iii) perchlorate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238638/ https://www.ncbi.nlm.nih.gov/pubmed/22199529 http://dx.doi.org/10.1107/S1600536811046484 |
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