catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]

In the title salt, {[Ho(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the anion forms a W/S/Ag polymeric chain along the a axis. The holmium atom in the cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands in a distorted square-anti­prismatic geometry. T...

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Detalles Bibliográficos
Autores principales: Zeng, Juxiang, Tang, Guodong, Wei, Changmei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238639/
https://www.ncbi.nlm.nih.gov/pubmed/22199530
http://dx.doi.org/10.1107/S1600536811046460
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author Zeng, Juxiang
Tang, Guodong
Wei, Changmei
author_facet Zeng, Juxiang
Tang, Guodong
Wei, Changmei
author_sort Zeng, Juxiang
collection PubMed
description In the title salt, {[Ho(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the anion forms a W/S/Ag polymeric chain along the a axis. The holmium atom in the cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands in a distorted square-anti­prismatic geometry. Together with the two nitrate ligands, the complex cation in the title compound is univalent, which leads the anion to be univalent as well. The polymeric anionic chain with W—Ag—W and Ag—W—Ag angles of 161.429 (17) and 153.608 (10) °, respectively, presents a distorted linear configuration. The title complex is isotypic with the corresponding Y, Yb, Eu, Nd, La and Dy analogues.
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spelling pubmed-32386392011-12-23 catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]] Zeng, Juxiang Tang, Guodong Wei, Changmei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, {[Ho(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), the anion forms a W/S/Ag polymeric chain along the a axis. The holmium atom in the cation is coordinated by eight O atoms from two nitrate and four hexa­methyl­phospho­ramide ligands in a distorted square-anti­prismatic geometry. Together with the two nitrate ligands, the complex cation in the title compound is univalent, which leads the anion to be univalent as well. The polymeric anionic chain with W—Ag—W and Ag—W—Ag angles of 161.429 (17) and 153.608 (10) °, respectively, presents a distorted linear configuration. The title complex is isotypic with the corresponding Y, Yb, Eu, Nd, La and Dy analogues. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238639/ /pubmed/22199530 http://dx.doi.org/10.1107/S1600536811046460 Text en © Zeng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zeng, Juxiang
Tang, Guodong
Wei, Changmei
catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_full catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_fullStr catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_full_unstemmed catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_short catena-Poly[[tetra­kis­(hexa­methyl­phospho­ramide-κO)bis­(nitrato-κ(2) O,O′)holmium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
title_sort catena-poly[[tetra­kis­(hexa­methyl­phospho­ramide-κo)bis­(nitrato-κ(2) o,o′)holmium(iii)] [silver(i)-di-μ-sulfido-tungstate(vi)-di-μ-sulfido]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238639/
https://www.ncbi.nlm.nih.gov/pubmed/22199530
http://dx.doi.org/10.1107/S1600536811046460
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AT weichangmei catenapolytetrakishexamethylphosphoramidekobisnitratok2ooholmiumiiisilveridimsulfidotungstatevidimsulfido

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