3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)

In the title compound, (C(8)H(15)N(2))[Ni(C(4)N(2)S(2))(2)], the Ni(III) atom is coordinated by four S atoms of two maleonitrile­dithiol­ate ligands and exhibits a distorted square-planar geometry. In the crystal, the cations and anions are connected alternately by weak inter­molecular C—H⋯N hydroge...

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Detalles Bibliográficos
Autor principal: Yu, Shan-Shan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238640/
https://www.ncbi.nlm.nih.gov/pubmed/22199531
http://dx.doi.org/10.1107/S1600536811046824
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author Yu, Shan-Shan
author_facet Yu, Shan-Shan
author_sort Yu, Shan-Shan
collection PubMed
description In the title compound, (C(8)H(15)N(2))[Ni(C(4)N(2)S(2))(2)], the Ni(III) atom is coordinated by four S atoms of two maleonitrile­dithiol­ate ligands and exhibits a distorted square-planar geometry. In the crystal, the cations and anions are connected alternately by weak inter­molecular C—H⋯N hydrogen bonds, forming a zigzag chain along [201].
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spelling pubmed-32386402011-12-23 3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III) Yu, Shan-Shan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(8)H(15)N(2))[Ni(C(4)N(2)S(2))(2)], the Ni(III) atom is coordinated by four S atoms of two maleonitrile­dithiol­ate ligands and exhibits a distorted square-planar geometry. In the crystal, the cations and anions are connected alternately by weak inter­molecular C—H⋯N hydrogen bonds, forming a zigzag chain along [201]. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238640/ /pubmed/22199531 http://dx.doi.org/10.1107/S1600536811046824 Text en © Shan-Shan Yu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yu, Shan-Shan
3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)
title 3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)
title_full 3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)
title_fullStr 3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)
title_full_unstemmed 3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)
title_short 3-Butyl-1-methyl-1H-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) S,S′)nickel(III)
title_sort 3-butyl-1-methyl-1h-imidazol-3-ium bis­(1,2-dicyano­ethene-1,2-dithiol­ato-κ(2) s,s′)nickel(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238640/
https://www.ncbi.nlm.nih.gov/pubmed/22199531
http://dx.doi.org/10.1107/S1600536811046824
work_keys_str_mv AT yushanshan 3butyl1methyl1himidazol3iumbis12dicyanoethene12dithiolatok2ssnickeliii

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