Cargando…

catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]

The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidate ligand via O,N,N′-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional site...

Descripción completa

Detalles Bibliográficos
Autores principales: Shahverdizadeh, Gholam Hossein, Tiekink, Edward R. T., Mirtamizdoust, Babak
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238642/
https://www.ncbi.nlm.nih.gov/pubmed/22199533
http://dx.doi.org/10.1107/S1600536811046769
_version_ 1782219028591280128
author Shahverdizadeh, Gholam Hossein
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_facet Shahverdizadeh, Gholam Hossein
Tiekink, Edward R. T.
Mirtamizdoust, Babak
author_sort Shahverdizadeh, Gholam Hossein
collection PubMed
description The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidate ligand via O,N,N′-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional sites are occupied by methanol O atoms. The resultant supra­molecular chain is a zigzag along the c axis. The Pb(II) atom is seven-coordinated within an N(3)O(3) donor set and a lone pair of electrons, which defines a Ψ-pentagonal–bipyramidal coordination geometry with the pyridine N and lone pair in axial positions. The supra­molecular chains are linked into the two-dimensional array via inter­molecular Pb⋯N [3.020 (4) Å] inter­actions. Layers stack along the a axis, being connected by O—H⋯O hydrogen bonds formed between the coordinated methanol mol­ecules and perchlorate anions.
format Online
Article
Text
id pubmed-3238642
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386422011-12-23 catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate] Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidate ligand via O,N,N′-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional sites are occupied by methanol O atoms. The resultant supra­molecular chain is a zigzag along the c axis. The Pb(II) atom is seven-coordinated within an N(3)O(3) donor set and a lone pair of electrons, which defines a Ψ-pentagonal–bipyramidal coordination geometry with the pyridine N and lone pair in axial positions. The supra­molecular chains are linked into the two-dimensional array via inter­molecular Pb⋯N [3.020 (4) Å] inter­actions. Layers stack along the a axis, being connected by O—H⋯O hydrogen bonds formed between the coordinated methanol mol­ecules and perchlorate anions. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238642/ /pubmed/22199533 http://dx.doi.org/10.1107/S1600536811046769 Text en © Shahverdizadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shahverdizadeh, Gholam Hossein
Tiekink, Edward R. T.
Mirtamizdoust, Babak
catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
title catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
title_full catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
title_fullStr catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
title_full_unstemmed catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
title_short catena-Poly[[[bis­(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethyl­idene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
title_sort catena-poly[[[bis­(methanol-κo)lead(ii)]-μ-n′-[1-(pyridin-2-yl-κn)ethyl­idene]isonicotinohydrazidato-κ(3) n′,o:n (1)] perchlorate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238642/
https://www.ncbi.nlm.nih.gov/pubmed/22199533
http://dx.doi.org/10.1107/S1600536811046769
work_keys_str_mv AT shahverdizadehgholamhossein catenapolybismethanolkoleadiimn1pyridin2ylknethylideneisonicotinohydrazidatok3non1perchlorate
AT tiekinkedwardrt catenapolybismethanolkoleadiimn1pyridin2ylknethylideneisonicotinohydrazidatok3non1perchlorate
AT mirtamizdoustbabak catenapolybismethanolkoleadiimn1pyridin2ylknethylideneisonicotinohydrazidatok3non1perchlorate