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catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate]
The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidate ligand via O,N,N′-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional site...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238642/ https://www.ncbi.nlm.nih.gov/pubmed/22199533 http://dx.doi.org/10.1107/S1600536811046769 |
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author | Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Mirtamizdoust, Babak |
author_facet | Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Mirtamizdoust, Babak |
author_sort | Shahverdizadeh, Gholam Hossein |
collection | PubMed |
description | The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidate ligand via O,N,N′-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional sites are occupied by methanol O atoms. The resultant supramolecular chain is a zigzag along the c axis. The Pb(II) atom is seven-coordinated within an N(3)O(3) donor set and a lone pair of electrons, which defines a Ψ-pentagonal–bipyramidal coordination geometry with the pyridine N and lone pair in axial positions. The supramolecular chains are linked into the two-dimensional array via intermolecular Pb⋯N [3.020 (4) Å] interactions. Layers stack along the a axis, being connected by O—H⋯O hydrogen bonds formed between the coordinated methanol molecules and perchlorate anions. |
format | Online Article Text |
id | pubmed-3238642 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386422011-12-23 catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate] Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Mirtamizdoust, Babak Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Pb(II) atom in the polymeric title compound, {[Pb(C(13)H(11)N(4)O)(CH(3)OH)(2)]ClO(4)}(n), is coordinated by an N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidate ligand via O,N,N′-donors and simultaneously bridged by a neighbouring ligand via the isonicotinoyl N atom; two additional sites are occupied by methanol O atoms. The resultant supramolecular chain is a zigzag along the c axis. The Pb(II) atom is seven-coordinated within an N(3)O(3) donor set and a lone pair of electrons, which defines a Ψ-pentagonal–bipyramidal coordination geometry with the pyridine N and lone pair in axial positions. The supramolecular chains are linked into the two-dimensional array via intermolecular Pb⋯N [3.020 (4) Å] interactions. Layers stack along the a axis, being connected by O—H⋯O hydrogen bonds formed between the coordinated methanol molecules and perchlorate anions. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238642/ /pubmed/22199533 http://dx.doi.org/10.1107/S1600536811046769 Text en © Shahverdizadeh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shahverdizadeh, Gholam Hossein Tiekink, Edward R. T. Mirtamizdoust, Babak catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3) N′,O:N (1)] perchlorate] |
title |
catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3)
N′,O:N
(1)] perchlorate] |
title_full |
catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3)
N′,O:N
(1)] perchlorate] |
title_fullStr |
catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3)
N′,O:N
(1)] perchlorate] |
title_full_unstemmed |
catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3)
N′,O:N
(1)] perchlorate] |
title_short |
catena-Poly[[[bis(methanol-κO)lead(II)]-μ-N′-[1-(pyridin-2-yl-κN)ethylidene]isonicotinohydrazidato-κ(3)
N′,O:N
(1)] perchlorate] |
title_sort | catena-poly[[[bis(methanol-κo)lead(ii)]-μ-n′-[1-(pyridin-2-yl-κn)ethylidene]isonicotinohydrazidato-κ(3)
n′,o:n
(1)] perchlorate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238642/ https://www.ncbi.nlm.nih.gov/pubmed/22199533 http://dx.doi.org/10.1107/S1600536811046769 |
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