Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate

In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa­hedral coordination environment. The solvent water mol­ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7...

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Detalles Bibliográficos
Autores principales: Xiao, Yunyun, Shen, Xiaoping, Li, Yizhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238645/
https://www.ncbi.nlm.nih.gov/pubmed/22199536
http://dx.doi.org/10.1107/S1600536811046800
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author Xiao, Yunyun
Shen, Xiaoping
Li, Yizhi
author_facet Xiao, Yunyun
Shen, Xiaoping
Li, Yizhi
author_sort Xiao, Yunyun
collection PubMed
description In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa­hedral coordination environment. The solvent water mol­ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data.
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spelling pubmed-32386452011-12-23 Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate Xiao, Yunyun Shen, Xiaoping Li, Yizhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(12)H(8)N(3)O(2))(2)][Fe(C(12)H(8)N(3)O(2))(CN)(3)]·H(2)O, the Fe(3+) ions in the cation and anion each lie in a slightly distorted octa­hedral coordination environment. The solvent water mol­ecule is disordered over three positions with occupancies of 0.401 (7), 0.322 (7) and 0.277 (6). The water content was confirmed by thermogravimetric data. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238645/ /pubmed/22199536 http://dx.doi.org/10.1107/S1600536811046800 Text en © Xiao et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xiao, Yunyun
Shen, Xiaoping
Li, Yizhi
Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate
title Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate
title_full Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate
title_fullStr Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate
title_full_unstemmed Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate
title_short Bis[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]iron(III) tris­(cyanido-κC)[N-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) N,N′,N′′]ferrate(III) monohydrate
title_sort bis[n-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) n,n′,n′′]iron(iii) tris­(cyanido-κc)[n-(pyridin-2-ylcarbon­yl)pyridine-2-carboximidato-κ(3) n,n′,n′′]ferrate(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238645/
https://www.ncbi.nlm.nih.gov/pubmed/22199536
http://dx.doi.org/10.1107/S1600536811046800
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