Bis(4-fluoro­benz­yl-κC)bis­(3-methyl­sulfanyl-1,2,4-thia­diazole-5-thiol­ato-κ(2) N (4),S (5))tin(IV)

The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal–bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methyl­sulfanyl-1,2,4-thia­diazole-5-thiol­ate ligands. The...

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Detalles Bibliográficos
Autores principales: Deng, Ai-Xia, Xie, Qian, Teng, Mou-Yong, Fu, Guo-Jia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238646/
https://www.ncbi.nlm.nih.gov/pubmed/22199537
http://dx.doi.org/10.1107/S1600536811046654
Descripción
Sumario:The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal–bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methyl­sulfanyl-1,2,4-thia­diazole-5-thiol­ate ligands. The apical positions are occupied by the C atoms of two 4-fluoro­benzyl groups.

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