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Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2) N (4),S (5))tin(IV)
The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal–bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methylsulfanyl-1,2,4-thiadiazole-5-thiolate ligands. The...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238646/ https://www.ncbi.nlm.nih.gov/pubmed/22199537 http://dx.doi.org/10.1107/S1600536811046654 |
| _version_ | 1782219029520318464 |
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| author | Deng, Ai-Xia Xie, Qian Teng, Mou-Yong Fu, Guo-Jia |
| author_facet | Deng, Ai-Xia Xie, Qian Teng, Mou-Yong Fu, Guo-Jia |
| author_sort | Deng, Ai-Xia |
| collection | PubMed |
| description | The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal–bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methylsulfanyl-1,2,4-thiadiazole-5-thiolate ligands. The apical positions are occupied by the C atoms of two 4-fluorobenzyl groups. |
| format | Online Article Text |
| id | pubmed-3238646 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386462011-12-23 Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2) N (4),S (5))tin(IV) Deng, Ai-Xia Xie, Qian Teng, Mou-Yong Fu, Guo-Jia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal–bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methylsulfanyl-1,2,4-thiadiazole-5-thiolate ligands. The apical positions are occupied by the C atoms of two 4-fluorobenzyl groups. International Union of Crystallography 2011-11-09 /pmc/articles/PMC3238646/ /pubmed/22199537 http://dx.doi.org/10.1107/S1600536811046654 Text en © Deng et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Deng, Ai-Xia Xie, Qian Teng, Mou-Yong Fu, Guo-Jia Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2) N (4),S (5))tin(IV) |
| title | Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2)
N
(4),S
(5))tin(IV) |
| title_full | Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2)
N
(4),S
(5))tin(IV) |
| title_fullStr | Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2)
N
(4),S
(5))tin(IV) |
| title_full_unstemmed | Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2)
N
(4),S
(5))tin(IV) |
| title_short | Bis(4-fluorobenzyl-κC)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2)
N
(4),S
(5))tin(IV) |
| title_sort | bis(4-fluorobenzyl-κc)bis(3-methylsulfanyl-1,2,4-thiadiazole-5-thiolato-κ(2)
n
(4),s
(5))tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238646/ https://www.ncbi.nlm.nih.gov/pubmed/22199537 http://dx.doi.org/10.1107/S1600536811046654 |
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