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Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate

In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxyl­ate O atom. The Co(II) atom adopts a sl...

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Detalles Bibliográficos
Autores principales: Yang, Guang-Rui, Li, Guo-Ting
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238654/
https://www.ncbi.nlm.nih.gov/pubmed/22199545
http://dx.doi.org/10.1107/S1600536811046526
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author Yang, Guang-Rui
Li, Guo-Ting
author_facet Yang, Guang-Rui
Li, Guo-Ting
author_sort Yang, Guang-Rui
collection PubMed
description In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxyl­ate O atom. The Co(II) atom adopts a slightly distorted octa­hedral coordination geometry with four O atoms of the coordinated water mol­ecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions. In the crystal, the components are connected through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional framework.
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spelling pubmed-32386542011-12-23 Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate Yang, Guang-Rui Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxyl­ate O atom. The Co(II) atom adopts a slightly distorted octa­hedral coordination geometry with four O atoms of the coordinated water mol­ecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions. In the crystal, the components are connected through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional framework. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238654/ /pubmed/22199545 http://dx.doi.org/10.1107/S1600536811046526 Text en © Yang and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Guang-Rui
Li, Guo-Ting
Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate
title Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate
title_full Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate
title_fullStr Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate
title_full_unstemmed Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate
title_short Tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(II) monohydrate
title_sort tetra­aqua­bis­(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfan­yl}acetato)­cobalt(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238654/
https://www.ncbi.nlm.nih.gov/pubmed/22199545
http://dx.doi.org/10.1107/S1600536811046526
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AT liguoting tetraaquabis25pyridin4yl134oxadiazol2ylsulfanylacetatocobaltiimonohydrate