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Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate
In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxylate O atom. The Co(II) atom adopts a sl...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238654/ https://www.ncbi.nlm.nih.gov/pubmed/22199545 http://dx.doi.org/10.1107/S1600536811046526 |
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author | Yang, Guang-Rui Li, Guo-Ting |
author_facet | Yang, Guang-Rui Li, Guo-Ting |
author_sort | Yang, Guang-Rui |
collection | PubMed |
description | In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxylate O atom. The Co(II) atom adopts a slightly distorted octahedral coordination geometry with four O atoms of the coordinated water molecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions. In the crystal, the components are connected through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional framework. |
format | Online Article Text |
id | pubmed-3238654 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386542011-12-23 Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate Yang, Guang-Rui Li, Guo-Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·H(2)O, the two 2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetate ligands are monodentate. One coordinates the metal atom via the pyridyl N atom whereas the other coordinates via the carboxylate O atom. The Co(II) atom adopts a slightly distorted octahedral coordination geometry with four O atoms of the coordinated water molecules located in the equatorial plane and the N and O atoms of the two POA ligands in axial positions. In the crystal, the components are connected through O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional framework. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238654/ /pubmed/22199545 http://dx.doi.org/10.1107/S1600536811046526 Text en © Yang and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Guang-Rui Li, Guo-Ting Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate |
title | Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate |
title_full | Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate |
title_fullStr | Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate |
title_full_unstemmed | Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate |
title_short | Tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(II) monohydrate |
title_sort | tetraaquabis(2-{[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetato)cobalt(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238654/ https://www.ncbi.nlm.nih.gov/pubmed/22199545 http://dx.doi.org/10.1107/S1600536811046526 |
work_keys_str_mv | AT yangguangrui tetraaquabis25pyridin4yl134oxadiazol2ylsulfanylacetatocobaltiimonohydrate AT liguoting tetraaquabis25pyridin4yl134oxadiazol2ylsulfanylacetatocobaltiimonohydrate |