[(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate

In the title compound, [Cu(C(24)H(27)N(4)O(3))]ClO(4), the Cu(II) atom has a distorted square-planar coordination geometry and is surrounded by an N(3)O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intra­molecular N—H⋯O hydrogen bond oc...

Descripción completa

Detalles Bibliográficos
Autores principales: Azadbakht, Reza, Amiri Rudbari, Hadi, Menati, Saeid, Bruno, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238655/
https://www.ncbi.nlm.nih.gov/pubmed/22199546
http://dx.doi.org/10.1107/S1600536811045752
_version_ 1782219031577624576
author Azadbakht, Reza
Amiri Rudbari, Hadi
Menati, Saeid
Bruno, Giuseppe
author_facet Azadbakht, Reza
Amiri Rudbari, Hadi
Menati, Saeid
Bruno, Giuseppe
author_sort Azadbakht, Reza
collection PubMed
description In the title compound, [Cu(C(24)H(27)N(4)O(3))]ClO(4), the Cu(II) atom has a distorted square-planar coordination geometry and is surrounded by an N(3)O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are held together by inter­molecular N—H⋯O hydrogen bonds, leading to the formation of a three-dimensional network.
format Online
Article
Text
id pubmed-3238655
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386552011-12-23 [(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate Azadbakht, Reza Amiri Rudbari, Hadi Menati, Saeid Bruno, Giuseppe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(24)H(27)N(4)O(3))]ClO(4), the Cu(II) atom has a distorted square-planar coordination geometry and is surrounded by an N(3)O donor set composed of a secondary amine N, a primary amine H, an imino N and a naphthalen-2-olate O atom. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are held together by inter­molecular N—H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238655/ /pubmed/22199546 http://dx.doi.org/10.1107/S1600536811045752 Text en © Azadbakht et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Azadbakht, Reza
Amiri Rudbari, Hadi
Menati, Saeid
Bruno, Giuseppe
[(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate
title [(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate
title_full [(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate
title_fullStr [(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate
title_full_unstemmed [(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate
title_short [(Z)-1-({3-[(3-Amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(II) perchlorate
title_sort [(z)-1-({3-[(3-amino­prop­yl)(2-nitro­benz­yl)amino]­prop­yl}imino­meth­yl)naphthalen-2-olato]copper(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238655/
https://www.ncbi.nlm.nih.gov/pubmed/22199546
http://dx.doi.org/10.1107/S1600536811045752
work_keys_str_mv AT azadbakhtreza z133aminopropyl2nitrobenzylaminopropyliminomethylnaphthalen2olatocopperiiperchlorate
AT amirirudbarihadi z133aminopropyl2nitrobenzylaminopropyliminomethylnaphthalen2olatocopperiiperchlorate
AT menatisaeid z133aminopropyl2nitrobenzylaminopropyliminomethylnaphthalen2olatocopperiiperchlorate
AT brunogiuseppe z133aminopropyl2nitrobenzylaminopropyliminomethylnaphthalen2olatocopperiiperchlorate

Ejemplares similares