Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate

In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]ClO(4), the Ag(I) ion is surrounded by two 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands, forming a considerably distorted square-planar N(4)-coordination geometry, with two short and two long Ag—N distances. Each perchlorate anion links two...

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Detalles Bibliográficos
Autores principales: Zhang, Fan, Wang, Zhi-Wei, Yang, Yong-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238656/
https://www.ncbi.nlm.nih.gov/pubmed/22199547
http://dx.doi.org/10.1107/S1600536811046708
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author Zhang, Fan
Wang, Zhi-Wei
Yang, Yong-Li
author_facet Zhang, Fan
Wang, Zhi-Wei
Yang, Yong-Li
author_sort Zhang, Fan
collection PubMed
description In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]ClO(4), the Ag(I) ion is surrounded by two 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands, forming a considerably distorted square-planar N(4)-coordination geometry, with two short and two long Ag—N distances. Each perchlorate anion links two mononuclear coordination units through C—H⋯O(perchlorate) hydrogen bonding, forming an infinite tape structure along [110]. Inter­molecular π–π stacking inter­actions between adjacent pyridine and pyrazine rings [centroid–centroid distances of 3.777 (3) and 3.879 (2) Å] further assemble the tape motifs into a three-dimensional supra­molecular structure.
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spelling pubmed-32386562011-12-23 Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate Zhang, Fan Wang, Zhi-Wei Yang, Yong-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Ag(C(10)H(6)N(4))(2)]ClO(4), the Ag(I) ion is surrounded by two 5-(pyridin-2-yl)pyrazine-2-carbonitrile ligands, forming a considerably distorted square-planar N(4)-coordination geometry, with two short and two long Ag—N distances. Each perchlorate anion links two mononuclear coordination units through C—H⋯O(perchlorate) hydrogen bonding, forming an infinite tape structure along [110]. Inter­molecular π–π stacking inter­actions between adjacent pyridine and pyrazine rings [centroid–centroid distances of 3.777 (3) and 3.879 (2) Å] further assemble the tape motifs into a three-dimensional supra­molecular structure. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238656/ /pubmed/22199547 http://dx.doi.org/10.1107/S1600536811046708 Text en © Zhang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Fan
Wang, Zhi-Wei
Yang, Yong-Li
Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate
title Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate
title_full Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate
title_fullStr Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate
title_full_unstemmed Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate
title_short Bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) N (4),N (5)]silver(I) perchlorate
title_sort bis[5-(pyridin-2-yl)pyrazine-2-carbo­nitrile-κ(2) n (4),n (5)]silver(i) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238656/
https://www.ncbi.nlm.nih.gov/pubmed/22199547
http://dx.doi.org/10.1107/S1600536811046708
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