Cargando…
Tetraaquabis[N,N′-bis(pyridin-3-ylmethylidene)benzene-1,4-diamine]zinc dinitrate 1.49-hydrate
In the title compound, [Zn(C(18)H(14)N(4))(2)(H(2)O)(4)](NO(3))(2)·1.49H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N,N′-bis(pyridin-3-ylmethylidene)benzene-1,4-diamine ligands and four water molecules in a distorted octahedral geometry. The nitra...
Autores principales: | , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238659/ https://www.ncbi.nlm.nih.gov/pubmed/22199550 http://dx.doi.org/10.1107/S1600536811046915 |
Sumario: | In the title compound, [Zn(C(18)H(14)N(4))(2)(H(2)O)(4)](NO(3))(2)·1.49H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N,N′-bis(pyridin-3-ylmethylidene)benzene-1,4-diamine ligands and four water molecules in a distorted octahedral geometry. The nitrate anion is disordered over two sets of sites, with an occupancy ratio of 0.744 (4):0.256 (4). The uncoordinated water molecule is also disordered with an occupancy factor of 0.744 (4). O—H⋯O and O—H⋯N hydrogen bonds link the complex cations, nitrate anions and uncoordinated water molecules into a supramolecular layer parallel to (102). |
---|