Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate

In the title compound, [Zn(C(18)H(14)N(4))(2)(H(2)O)(4)](NO(3))(2)·1.49H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine ligands and four water mol­ecules in a distorted octa­hedral geometry. The nitra...

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Detalles Bibliográficos
Autores principales: Kong, Li, Yu, Haihui, Zhang, Jibo, Cui, Weiyi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238659/
https://www.ncbi.nlm.nih.gov/pubmed/22199550
http://dx.doi.org/10.1107/S1600536811046915
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author Kong, Li
Yu, Haihui
Zhang, Jibo
Cui, Weiyi
author_facet Kong, Li
Yu, Haihui
Zhang, Jibo
Cui, Weiyi
author_sort Kong, Li
collection PubMed
description In the title compound, [Zn(C(18)H(14)N(4))(2)(H(2)O)(4)](NO(3))(2)·1.49H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine ligands and four water mol­ecules in a distorted octa­hedral geometry. The nitrate anion is disordered over two sets of sites, with an occupancy ratio of 0.744 (4):0.256 (4). The uncoordinated water mol­ecule is also disordered with an occupancy factor of 0.744 (4). O—H⋯O and O—H⋯N hydrogen bonds link the complex cations, nitrate anions and uncoordinated water mol­ecules into a supra­molecular layer parallel to (102).
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spelling pubmed-32386592011-12-23 Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate Kong, Li Yu, Haihui Zhang, Jibo Cui, Weiyi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(18)H(14)N(4))(2)(H(2)O)(4)](NO(3))(2)·1.49H(2)O, the Zn(II) atom, lying on an inversion center, is coordinated by two N atoms from two N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine ligands and four water mol­ecules in a distorted octa­hedral geometry. The nitrate anion is disordered over two sets of sites, with an occupancy ratio of 0.744 (4):0.256 (4). The uncoordinated water mol­ecule is also disordered with an occupancy factor of 0.744 (4). O—H⋯O and O—H⋯N hydrogen bonds link the complex cations, nitrate anions and uncoordinated water mol­ecules into a supra­molecular layer parallel to (102). International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238659/ /pubmed/22199550 http://dx.doi.org/10.1107/S1600536811046915 Text en © Kong et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kong, Li
Yu, Haihui
Zhang, Jibo
Cui, Weiyi
Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
title Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
title_full Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
title_fullStr Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
title_full_unstemmed Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
title_short Tetra­aqua­bis­[N,N′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
title_sort tetra­aqua­bis­[n,n′-bis­(pyridin-3-yl­methyl­idene)benzene-1,4-diamine]­zinc dinitrate 1.49-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238659/
https://www.ncbi.nlm.nih.gov/pubmed/22199550
http://dx.doi.org/10.1107/S1600536811046915
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AT zhangjibo tetraaquabisnnbispyridin3ylmethylidenebenzene14diaminezincdinitrate149hydrate
AT cuiweiyi tetraaquabisnnbispyridin3ylmethylidenebenzene14diaminezincdinitrate149hydrate

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