Cargando…
Pentacarbonyl-1κ(2) C,2κ(3) C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4) S,S′:S,S′)iron(I)(Fe—Fe)
In the title compound, [Fe(2)(C(7)H(4)IN)(C(3)H(6)S(2))(CO)(5)], the Fe—Fe distance of 2.5156 (11) Å compares well with that in related model structures. The phenyl isocyanide ligand is in the basal position and trans to the S atoms of the propanedithiolate ligand due to steric hindrance. The crys...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238660/ https://www.ncbi.nlm.nih.gov/pubmed/22199551 http://dx.doi.org/10.1107/S1600536811047088 |
| _version_ | 1782219032716378112 |
|---|---|
| author | Zhu, Jinli Tang, Yanfeng Jiang, Guo -Min Wang, Miao Hua, Ping |
| author_facet | Zhu, Jinli Tang, Yanfeng Jiang, Guo -Min Wang, Miao Hua, Ping |
| author_sort | Zhu, Jinli |
| collection | PubMed |
| description | In the title compound, [Fe(2)(C(7)H(4)IN)(C(3)H(6)S(2))(CO)(5)], the Fe—Fe distance of 2.5156 (11) Å compares well with that in related model structures. The phenyl isocyanide ligand is in the basal position and trans to the S atoms of the propanedithiolate ligand due to steric hindrance. The crystal structure features C—H⋯O interactions. |
| format | Online Article Text |
| id | pubmed-3238660 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386602011-12-23 Pentacarbonyl-1κ(2) C,2κ(3) C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4) S,S′:S,S′)iron(I)(Fe—Fe) Zhu, Jinli Tang, Yanfeng Jiang, Guo -Min Wang, Miao Hua, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(2)(C(7)H(4)IN)(C(3)H(6)S(2))(CO)(5)], the Fe—Fe distance of 2.5156 (11) Å compares well with that in related model structures. The phenyl isocyanide ligand is in the basal position and trans to the S atoms of the propanedithiolate ligand due to steric hindrance. The crystal structure features C—H⋯O interactions. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238660/ /pubmed/22199551 http://dx.doi.org/10.1107/S1600536811047088 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhu, Jinli Tang, Yanfeng Jiang, Guo -Min Wang, Miao Hua, Ping Pentacarbonyl-1κ(2) C,2κ(3) C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4) S,S′:S,S′)iron(I)(Fe—Fe) |
| title | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′)iron(I)(Fe—Fe) |
| title_full | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′)iron(I)(Fe—Fe) |
| title_fullStr | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′)iron(I)(Fe—Fe) |
| title_full_unstemmed | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′)iron(I)(Fe—Fe) |
| title_short | Pentacarbonyl-1κ(2)
C,2κ(3)
C-(4-iodophenyl isocyanide-1κC)(μ-propane-1,3-dithiolato-1:2κ(4)
S,S′:S,S′)iron(I)(Fe—Fe) |
| title_sort | pentacarbonyl-1κ(2)
c,2κ(3)
c-(4-iodophenyl isocyanide-1κc)(μ-propane-1,3-dithiolato-1:2κ(4)
s,s′:s,s′)iron(i)(fe—fe) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238660/ https://www.ncbi.nlm.nih.gov/pubmed/22199551 http://dx.doi.org/10.1107/S1600536811047088 |
| work_keys_str_mv | AT zhujinli pentacarbonyl1k2c2k3c4iodophenylisocyanide1kcmpropane13dithiolato12k4ssssironifefe AT tangyanfeng pentacarbonyl1k2c2k3c4iodophenylisocyanide1kcmpropane13dithiolato12k4ssssironifefe AT jiangguomin pentacarbonyl1k2c2k3c4iodophenylisocyanide1kcmpropane13dithiolato12k4ssssironifefe AT wangmiao pentacarbonyl1k2c2k3c4iodophenylisocyanide1kcmpropane13dithiolato12k4ssssironifefe AT huaping pentacarbonyl1k2c2k3c4iodophenylisocyanide1kcmpropane13dithiolato12k4ssssironifefe |