1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)

In the title compound, (C(20)H(20)N(4))[HgCl(4)], the Hg(II) ion is four-coordinated in a tetra­hedral environment defined by four chloride ions. The dihedral angle between the two phenyl rings is 32.83 (15)°. The protonated 1,1′-[(biphenyl-4,4′-di­yl)bis­(meth­yl­ene)]di-1H-imidazol-3-ium cations,...

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Detalles Bibliográficos
Autores principales: Wen, Bo, Hou, Guang-Feng, Yu, Ying-Hui, Gao, Jin-Sheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238662/
https://www.ncbi.nlm.nih.gov/pubmed/22199553
http://dx.doi.org/10.1107/S1600536811047374
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author Wen, Bo
Hou, Guang-Feng
Yu, Ying-Hui
Gao, Jin-Sheng
author_facet Wen, Bo
Hou, Guang-Feng
Yu, Ying-Hui
Gao, Jin-Sheng
author_sort Wen, Bo
collection PubMed
description In the title compound, (C(20)H(20)N(4))[HgCl(4)], the Hg(II) ion is four-coordinated in a tetra­hedral environment defined by four chloride ions. The dihedral angle between the two phenyl rings is 32.83 (15)°. The protonated 1,1′-[(biphenyl-4,4′-di­yl)bis­(meth­yl­ene)]di-1H-imidazol-3-ium cations, showing a cis conformation, link the [HgCl(4)](2−) anions into an R (4) (4)(42) motif via N—H⋯Cl hydrogen bonds.
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spelling pubmed-32386622011-12-23 1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II) Wen, Bo Hou, Guang-Feng Yu, Ying-Hui Gao, Jin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(20)H(20)N(4))[HgCl(4)], the Hg(II) ion is four-coordinated in a tetra­hedral environment defined by four chloride ions. The dihedral angle between the two phenyl rings is 32.83 (15)°. The protonated 1,1′-[(biphenyl-4,4′-di­yl)bis­(meth­yl­ene)]di-1H-imidazol-3-ium cations, showing a cis conformation, link the [HgCl(4)](2−) anions into an R (4) (4)(42) motif via N—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238662/ /pubmed/22199553 http://dx.doi.org/10.1107/S1600536811047374 Text en © Wen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Bo
Hou, Guang-Feng
Yu, Ying-Hui
Gao, Jin-Sheng
1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)
title 1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)
title_full 1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)
title_fullStr 1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)
title_full_unstemmed 1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)
title_short 1,1′-[(Biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1H-imidazol-3-ium tetra­chlorido­mercurate(II)
title_sort 1,1′-[(biphenyl-4,4′-di­yl)bis­(methyl­ene)]di-1h-imidazol-3-ium tetra­chlorido­mercurate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238662/
https://www.ncbi.nlm.nih.gov/pubmed/22199553
http://dx.doi.org/10.1107/S1600536811047374
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