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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3) N (3),O:N (1)]
In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonatobenzotriazolide dianions, two N atoms from a 1,10-phenanthroline molecule and a sulfonate O atom from a 4-sulfonatobenzotriazolide anion, displaying a distorted ZnN...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238664/ https://www.ncbi.nlm.nih.gov/pubmed/22199555 http://dx.doi.org/10.1107/S160053681104743X |
Sumario: | In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonatobenzotriazolide dianions, two N atoms from a 1,10-phenanthroline molecule and a sulfonate O atom from a 4-sulfonatobenzotriazolide anion, displaying a distorted ZnN(4)O trigonal–bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonatobenzotriazolide ions act as μ(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C—H⋯O hydrogen-bonding interactions. |
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