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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]

In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato­benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol­ecule and a sulfonate O atom from a 4-sulfonato­benzotriazolide anion, displaying a distorted ZnN...

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Autor principal: Cheng, Xiao-Chun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238664/
https://www.ncbi.nlm.nih.gov/pubmed/22199555
http://dx.doi.org/10.1107/S160053681104743X
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author Cheng, Xiao-Chun
author_facet Cheng, Xiao-Chun
author_sort Cheng, Xiao-Chun
collection PubMed
description In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato­benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol­ecule and a sulfonate O atom from a 4-sulfonato­benzotriazolide anion, displaying a distorted ZnN(4)O trigonal–bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonato­benzotriazolide ions act as μ(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-32386642011-12-23 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)] Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonato­benzotriazolide dianions, two N atoms from a 1,10-phenanthroline mol­ecule and a sulfonate O atom from a 4-sulfonato­benzotriazolide anion, displaying a distorted ZnN(4)O trigonal–bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonato­benzotriazolide ions act as μ(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238664/ /pubmed/22199555 http://dx.doi.org/10.1107/S160053681104743X Text en © Xiao-Chun Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cheng, Xiao-Chun
catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]
title catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]
title_full catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]
title_fullStr catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]
title_short catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) N (3),O:N (1)]
title_sort catena-poly[[(1,10-phenanthroline-κ(2) n,n′)zinc]-μ-4-sulfonato­benzo­triazolido-κ(3) n (3),o:n (1)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238664/
https://www.ncbi.nlm.nih.gov/pubmed/22199555
http://dx.doi.org/10.1107/S160053681104743X
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