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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3) N (3),O:N (1)]
In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonatobenzotriazolide dianions, two N atoms from a 1,10-phenanthroline molecule and a sulfonate O atom from a 4-sulfonatobenzotriazolide anion, displaying a distorted ZnN...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238664/ https://www.ncbi.nlm.nih.gov/pubmed/22199555 http://dx.doi.org/10.1107/S160053681104743X |
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author | Cheng, Xiao-Chun |
author_facet | Cheng, Xiao-Chun |
author_sort | Cheng, Xiao-Chun |
collection | PubMed |
description | In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonatobenzotriazolide dianions, two N atoms from a 1,10-phenanthroline molecule and a sulfonate O atom from a 4-sulfonatobenzotriazolide anion, displaying a distorted ZnN(4)O trigonal–bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonatobenzotriazolide ions act as μ(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C—H⋯O hydrogen-bonding interactions. |
format | Online Article Text |
id | pubmed-3238664 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386642011-12-23 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3) N (3),O:N (1)] Cheng, Xiao-Chun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(6)H(3)N(3)O(3)S)(C(12)H(8)N(2))](n), the Zn(2+) cation is coordinated by two N atoms from two 4-sulfonatobenzotriazolide dianions, two N atoms from a 1,10-phenanthroline molecule and a sulfonate O atom from a 4-sulfonatobenzotriazolide anion, displaying a distorted ZnN(4)O trigonal–bipyramidal geometry. Each 1,10-phenanthroline ligand displays a bidentate chelating coordinating mode and the 4-sulfonatobenzotriazolide ions act as μ(2)-bridges, linking different Zn(2+) cations into a chain along the b axis. The crystal structure is consolidated by C—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238664/ /pubmed/22199555 http://dx.doi.org/10.1107/S160053681104743X Text en © Xiao-Chun Cheng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cheng, Xiao-Chun catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3) N (3),O:N (1)] |
title |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3)
N
(3),O:N
(1)] |
title_full |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3)
N
(3),O:N
(1)] |
title_fullStr |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3)
N
(3),O:N
(1)] |
title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3)
N
(3),O:N
(1)] |
title_short |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3)
N
(3),O:N
(1)] |
title_sort | catena-poly[[(1,10-phenanthroline-κ(2)
n,n′)zinc]-μ-4-sulfonatobenzotriazolido-κ(3)
n
(3),o:n
(1)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238664/ https://www.ncbi.nlm.nih.gov/pubmed/22199555 http://dx.doi.org/10.1107/S160053681104743X |
work_keys_str_mv | AT chengxiaochun catenapoly110phenanthrolinek2nnzincm4sulfonatobenzotriazolidok3n3on1 |