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4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)

The structure of the title compound, (C(15)H(15)N(2)O(4))[AgI(2)], consists of an organic 4-[3-(isonicotino­yloxy)propoxycarbon­yl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the ali...

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Autores principales: Vallejos, Javier, Brito, Iván, Cárdenas, Alejandro, Bolte, Michael, López-Rodríguez, Matías
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238665/
https://www.ncbi.nlm.nih.gov/pubmed/22199556
http://dx.doi.org/10.1107/S1600536811047295
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author Vallejos, Javier
Brito, Iván
Cárdenas, Alejandro
Bolte, Michael
López-Rodríguez, Matías
author_facet Vallejos, Javier
Brito, Iván
Cárdenas, Alejandro
Bolte, Michael
López-Rodríguez, Matías
author_sort Vallejos, Javier
collection PubMed
description The structure of the title compound, (C(15)H(15)N(2)O(4))[AgI(2)], consists of an organic 4-[3-(isonicotino­yloxy)propoxycarbon­yl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the aliphatic chain, and an inorganic [AgI(2)](−) anion. In the complex anion, the Ag(+) cation is bound to two I(−) anions in a linear geometry. The anion was modelled assuming disorder around a crystallographic inversion centre near the location of the Ag(+) cation. The crystal packing is stabilized by a strong inter­molecular N—H⋯N hydrogen bond, which links the cations into zigzag chains with graph-set notation C(16) running along the face diagonal of the ac plane. The N-bound H atom is disordered over two equally occupied symmetry-equivalent sites, so that the mol­ecule has a pyridinium ring at one end and a pyridine ring at the other.
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spelling pubmed-32386652011-12-23 4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I) Vallejos, Javier Brito, Iván Cárdenas, Alejandro Bolte, Michael López-Rodríguez, Matías Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(15)H(15)N(2)O(4))[AgI(2)], consists of an organic 4-[3-(isonicotino­yloxy)propoxycarbon­yl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the aliphatic chain, and an inorganic [AgI(2)](−) anion. In the complex anion, the Ag(+) cation is bound to two I(−) anions in a linear geometry. The anion was modelled assuming disorder around a crystallographic inversion centre near the location of the Ag(+) cation. The crystal packing is stabilized by a strong inter­molecular N—H⋯N hydrogen bond, which links the cations into zigzag chains with graph-set notation C(16) running along the face diagonal of the ac plane. The N-bound H atom is disordered over two equally occupied symmetry-equivalent sites, so that the mol­ecule has a pyridinium ring at one end and a pyridine ring at the other. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238665/ /pubmed/22199556 http://dx.doi.org/10.1107/S1600536811047295 Text en © Vallejos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vallejos, Javier
Brito, Iván
Cárdenas, Alejandro
Bolte, Michael
López-Rodríguez, Matías
4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)
title 4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)
title_full 4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)
title_fullStr 4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)
title_full_unstemmed 4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)
title_short 4-[3-(Isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(I)
title_sort 4-[3-(isonicotino­yloxy)propoxycarbon­yl]pyridinium diiodidoargentate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238665/
https://www.ncbi.nlm.nih.gov/pubmed/22199556
http://dx.doi.org/10.1107/S1600536811047295
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