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4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I)
The structure of the title compound, (C(15)H(15)N(2)O(4))[AgI(2)], consists of an organic 4-[3-(isonicotinoyloxy)propoxycarbonyl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the ali...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238665/ https://www.ncbi.nlm.nih.gov/pubmed/22199556 http://dx.doi.org/10.1107/S1600536811047295 |
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author | Vallejos, Javier Brito, Iván Cárdenas, Alejandro Bolte, Michael López-Rodríguez, Matías |
author_facet | Vallejos, Javier Brito, Iván Cárdenas, Alejandro Bolte, Michael López-Rodríguez, Matías |
author_sort | Vallejos, Javier |
collection | PubMed |
description | The structure of the title compound, (C(15)H(15)N(2)O(4))[AgI(2)], consists of an organic 4-[3-(isonicotinoyloxy)propoxycarbonyl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the aliphatic chain, and an inorganic [AgI(2)](−) anion. In the complex anion, the Ag(+) cation is bound to two I(−) anions in a linear geometry. The anion was modelled assuming disorder around a crystallographic inversion centre near the location of the Ag(+) cation. The crystal packing is stabilized by a strong intermolecular N—H⋯N hydrogen bond, which links the cations into zigzag chains with graph-set notation C(16) running along the face diagonal of the ac plane. The N-bound H atom is disordered over two equally occupied symmetry-equivalent sites, so that the molecule has a pyridinium ring at one end and a pyridine ring at the other. |
format | Online Article Text |
id | pubmed-3238665 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386652011-12-23 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) Vallejos, Javier Brito, Iván Cárdenas, Alejandro Bolte, Michael López-Rodríguez, Matías Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, (C(15)H(15)N(2)O(4))[AgI(2)], consists of an organic 4-[3-(isonicotinoyloxy)propoxycarbonyl]pyridinium cation which has a gauche–gauche (O/C/C/C—O/C/C/C or GG’) conformation and lies on a twofold rotation axis, which passes through the central C atom of the aliphatic chain, and an inorganic [AgI(2)](−) anion. In the complex anion, the Ag(+) cation is bound to two I(−) anions in a linear geometry. The anion was modelled assuming disorder around a crystallographic inversion centre near the location of the Ag(+) cation. The crystal packing is stabilized by a strong intermolecular N—H⋯N hydrogen bond, which links the cations into zigzag chains with graph-set notation C(16) running along the face diagonal of the ac plane. The N-bound H atom is disordered over two equally occupied symmetry-equivalent sites, so that the molecule has a pyridinium ring at one end and a pyridine ring at the other. International Union of Crystallography 2011-11-12 /pmc/articles/PMC3238665/ /pubmed/22199556 http://dx.doi.org/10.1107/S1600536811047295 Text en © Vallejos et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Vallejos, Javier Brito, Iván Cárdenas, Alejandro Bolte, Michael López-Rodríguez, Matías 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) |
title | 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) |
title_full | 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) |
title_fullStr | 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) |
title_full_unstemmed | 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) |
title_short | 4-[3-(Isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(I) |
title_sort | 4-[3-(isonicotinoyloxy)propoxycarbonyl]pyridinium diiodidoargentate(i) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238665/ https://www.ncbi.nlm.nih.gov/pubmed/22199556 http://dx.doi.org/10.1107/S1600536811047295 |
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