Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate

In the title compound, [Fe(C(5)H(5))(C(17)H(16)NO(4))], the O=C—C=C—N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclo­penta­dienyl rings by 44.2 (2) and 13.8 (3)°, respectively. Furthermore, the O=C—C=C—N mean plane and the O=C—O(ester) plane make a dihedra...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhu, Bei-Bei, Shi, Yao-Cheng, Zhang, Feng-Min, Yuan, Li-Min, Li, Qian-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238666/
https://www.ncbi.nlm.nih.gov/pubmed/22199557
http://dx.doi.org/10.1107/S1600536811047763
_version_ 1782219034088964096
author Zhu, Bei-Bei
Shi, Yao-Cheng
Zhang, Feng-Min
Yuan, Li-Min
Li, Qian-Kun
author_facet Zhu, Bei-Bei
Shi, Yao-Cheng
Zhang, Feng-Min
Yuan, Li-Min
Li, Qian-Kun
author_sort Zhu, Bei-Bei
collection PubMed
description In the title compound, [Fe(C(5)H(5))(C(17)H(16)NO(4))], the O=C—C=C—N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclo­penta­dienyl rings by 44.2 (2) and 13.8 (3)°, respectively. Furthermore, the O=C—C=C—N mean plane and the O=C—O(ester) plane make a dihedral angle of 55.5 (6)°. Consistent with this large dihedral angle, the linking C—C bond [1.507 (6) Å] does not show any (delocalized) double-bond character.
format Online
Article
Text
id pubmed-3238666
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386662011-12-23 Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate Zhu, Bei-Bei Shi, Yao-Cheng Zhang, Feng-Min Yuan, Li-Min Li, Qian-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(17)H(16)NO(4))], the O=C—C=C—N mean plane is twisted with respect to the mean planes of the benzene and substituted cyclo­penta­dienyl rings by 44.2 (2) and 13.8 (3)°, respectively. Furthermore, the O=C—C=C—N mean plane and the O=C—O(ester) plane make a dihedral angle of 55.5 (6)°. Consistent with this large dihedral angle, the linking C—C bond [1.507 (6) Å] does not show any (delocalized) double-bond character. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238666/ /pubmed/22199557 http://dx.doi.org/10.1107/S1600536811047763 Text en © Zhu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Bei-Bei
Shi, Yao-Cheng
Zhang, Feng-Min
Yuan, Li-Min
Li, Qian-Kun
Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
title Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
title_full Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
title_fullStr Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
title_full_unstemmed Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
title_short Ethyl (Z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
title_sort ethyl (z)-4-ferrocenyl-2-(4-hy­droxy­anilino)-4-oxobutenoate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238666/
https://www.ncbi.nlm.nih.gov/pubmed/22199557
http://dx.doi.org/10.1107/S1600536811047763
work_keys_str_mv AT zhubeibei ethylz4ferrocenyl24hydroxyanilino4oxobutenoate
AT shiyaocheng ethylz4ferrocenyl24hydroxyanilino4oxobutenoate
AT zhangfengmin ethylz4ferrocenyl24hydroxyanilino4oxobutenoate
AT yuanlimin ethylz4ferrocenyl24hydroxyanilino4oxobutenoate
AT liqiankun ethylz4ferrocenyl24hydroxyanilino4oxobutenoate

Ejemplares similares