catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]

In the title polymer, [ZnCl(2)(C(11)H(8)N(2)O)](n), the Zn(II) atom lies on a twofold rotation axis and has a distorted tetra­hedral ZnCl(2)N(2) geometry involving two chloride donors and two N-atom donors from μ(2)-bridging bis­(pyridin-3-yl)methanone ligands, which also have twofold symmetry. A zi...

Descripción completa

Detalles Bibliográficos
Autor principal: Zhang, Fan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238669/
https://www.ncbi.nlm.nih.gov/pubmed/22199560
http://dx.doi.org/10.1107/S160053681104671X
_version_ 1782219034811432960
author Zhang, Fan
author_facet Zhang, Fan
author_sort Zhang, Fan
collection PubMed
description In the title polymer, [ZnCl(2)(C(11)H(8)N(2)O)](n), the Zn(II) atom lies on a twofold rotation axis and has a distorted tetra­hedral ZnCl(2)N(2) geometry involving two chloride donors and two N-atom donors from μ(2)-bridging bis­(pyridin-3-yl)methanone ligands, which also have twofold symmetry. A zigzag chain structure is formed, extending along (001). Each chain is surrounded by three others which are inter­connected through weak C=O⋯π(pyrid­yl) [O⋯centroid = 2.999 (3) Å] and π(pyrid­yl)–π(pyrid­yl) inter­actions [minimum ring centroid separation = 4.014 (2) Å], giving a three-dimensional framework.
format Online
Article
Text
id pubmed-3238669
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-32386692011-12-23 catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′] Zhang, Fan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymer, [ZnCl(2)(C(11)H(8)N(2)O)](n), the Zn(II) atom lies on a twofold rotation axis and has a distorted tetra­hedral ZnCl(2)N(2) geometry involving two chloride donors and two N-atom donors from μ(2)-bridging bis­(pyridin-3-yl)methanone ligands, which also have twofold symmetry. A zigzag chain structure is formed, extending along (001). Each chain is surrounded by three others which are inter­connected through weak C=O⋯π(pyrid­yl) [O⋯centroid = 2.999 (3) Å] and π(pyrid­yl)–π(pyrid­yl) inter­actions [minimum ring centroid separation = 4.014 (2) Å], giving a three-dimensional framework. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238669/ /pubmed/22199560 http://dx.doi.org/10.1107/S160053681104671X Text en © Fan Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Fan
catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]
title catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]
title_full catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]
title_fullStr catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]
title_full_unstemmed catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]
title_short catena-Poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) N:N′]
title_sort catena-poly[(dichloridozinc)-μ-bis­(pyridin-3-yl)methanone-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238669/
https://www.ncbi.nlm.nih.gov/pubmed/22199560
http://dx.doi.org/10.1107/S160053681104671X
work_keys_str_mv AT zhangfan catenapolydichloridozincmbispyridin3ylmethanonek2nn

Ejemplares similares