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Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4) O (1):O (6),O (6′):O (6′′))strontium(II)] monohydrate]
In the crystal structure of the polymeric title compound, {[Sr(C(10)H(6)O(6)S(2))(H(2)O)(4)]·H(2)O}(n), the naphthalene-1,6-disulfonate dianion uses one –SO(3) unit to O,O′-chelate to an Sr(II) cation and its third O atom to bind to another Sr(II) cation. The other –SO(3) unit binds to yet another S...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238671/ https://www.ncbi.nlm.nih.gov/pubmed/22199562 http://dx.doi.org/10.1107/S1600536811047593 |
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author | Gao, Shan Ng, Seik Weng |
author_facet | Gao, Shan Ng, Seik Weng |
author_sort | Gao, Shan |
collection | PubMed |
description | In the crystal structure of the polymeric title compound, {[Sr(C(10)H(6)O(6)S(2))(H(2)O)(4)]·H(2)O}(n), the naphthalene-1,6-disulfonate dianion uses one –SO(3) unit to O,O′-chelate to an Sr(II) cation and its third O atom to bind to another Sr(II) cation. The other –SO(3) unit binds to yet another Sr(II) atom. The four coordinated water molecules are monodentate but one is disordered over two positions in a 1:1 ratio. The μ(3)-bonding mode of the dianion generates a polymeric three-dimensional network; the network is consolidated by O—H⋯O hydrogen bonds. The Sr(II) cation exists in an undefined eight-coordinate environment. |
format | Online Article Text |
id | pubmed-3238671 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386712011-12-23 Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4) O (1):O (6),O (6′):O (6′′))strontium(II)] monohydrate] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the polymeric title compound, {[Sr(C(10)H(6)O(6)S(2))(H(2)O)(4)]·H(2)O}(n), the naphthalene-1,6-disulfonate dianion uses one –SO(3) unit to O,O′-chelate to an Sr(II) cation and its third O atom to bind to another Sr(II) cation. The other –SO(3) unit binds to yet another Sr(II) atom. The four coordinated water molecules are monodentate but one is disordered over two positions in a 1:1 ratio. The μ(3)-bonding mode of the dianion generates a polymeric three-dimensional network; the network is consolidated by O—H⋯O hydrogen bonds. The Sr(II) cation exists in an undefined eight-coordinate environment. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238671/ /pubmed/22199562 http://dx.doi.org/10.1107/S1600536811047593 Text en © Gao and Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gao, Shan Ng, Seik Weng Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4) O (1):O (6),O (6′):O (6′′))strontium(II)] monohydrate] |
title | Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4)
O
(1):O
(6),O
(6′):O
(6′′))strontium(II)] monohydrate] |
title_full | Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4)
O
(1):O
(6),O
(6′):O
(6′′))strontium(II)] monohydrate] |
title_fullStr | Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4)
O
(1):O
(6),O
(6′):O
(6′′))strontium(II)] monohydrate] |
title_full_unstemmed | Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4)
O
(1):O
(6),O
(6′):O
(6′′))strontium(II)] monohydrate] |
title_short | Poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4)
O
(1):O
(6),O
(6′):O
(6′′))strontium(II)] monohydrate] |
title_sort | poly[[tetraaqua(μ(3)-naphthalene-1,6-disulfonato-κ(4)
o
(1):o
(6),o
(6′):o
(6′′))strontium(ii)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238671/ https://www.ncbi.nlm.nih.gov/pubmed/22199562 http://dx.doi.org/10.1107/S1600536811047593 |
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