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Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)

In the binuclear title compound, [Ag(2)(C(11)H(11)N(3))(2)](CF(3)O(3)S)(2), the complex cation is centrosymmetric, with the unique Ag(+) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridin-2-ylmeth­yl)pyridin-2-amine ligands in a geometry slightly distorted from linear [N...

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Detalles Bibliográficos
Autores principales: Moon, Suk-Hee, Kim, Tae Ho, Park, Ki-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238672/
https://www.ncbi.nlm.nih.gov/pubmed/22199563
http://dx.doi.org/10.1107/S1600536811047908
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author Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_facet Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
author_sort Moon, Suk-Hee
collection PubMed
description In the binuclear title compound, [Ag(2)(C(11)H(11)N(3))(2)](CF(3)O(3)S)(2), the complex cation is centrosymmetric, with the unique Ag(+) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridin-2-ylmeth­yl)pyridin-2-amine ligands in a geometry slightly distorted from linear [N—Ag—N 161.02 (7)°]. This set-up leads to the formation of a 14-membered cyclic dimer. The two pyridine rings coordinated to the Ag(+) cation are tilted by 80.19 (7)° with respect to each other. Inter­molecular N—H⋯O hydrogen-bonding inter­actions between the cyclic dimer and the anion exist. A two-dimensional network parallel to the ac plane is constructed by three weak Ag⋯(O,N) inter­actions as well as an F⋯F contact of 2.890 (4) Å.
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spelling pubmed-32386722011-12-23 Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate) Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title compound, [Ag(2)(C(11)H(11)N(3))(2)](CF(3)O(3)S)(2), the complex cation is centrosymmetric, with the unique Ag(+) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridin-2-ylmeth­yl)pyridin-2-amine ligands in a geometry slightly distorted from linear [N—Ag—N 161.02 (7)°]. This set-up leads to the formation of a 14-membered cyclic dimer. The two pyridine rings coordinated to the Ag(+) cation are tilted by 80.19 (7)° with respect to each other. Inter­molecular N—H⋯O hydrogen-bonding inter­actions between the cyclic dimer and the anion exist. A two-dimensional network parallel to the ac plane is constructed by three weak Ag⋯(O,N) inter­actions as well as an F⋯F contact of 2.890 (4) Å. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238672/ /pubmed/22199563 http://dx.doi.org/10.1107/S1600536811047908 Text en © Moon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Moon, Suk-Hee
Kim, Tae Ho
Park, Ki-Min
Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)
title Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)
title_full Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)
title_fullStr Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)
title_full_unstemmed Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)
title_short Bis[μ-N-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoro­methane­sulfonate)
title_sort bis[μ-n-(pyridin-2-ylmeth­yl)pyridin-2-amine-κ(2) n:n′]disilver(i) bis(trifluoro­methane­sulfonate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238672/
https://www.ncbi.nlm.nih.gov/pubmed/22199563
http://dx.doi.org/10.1107/S1600536811047908
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