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Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoromethanesulfonate)
In the binuclear title compound, [Ag(2)(C(11)H(11)N(3))(2)](CF(3)O(3)S)(2), the complex cation is centrosymmetric, with the unique Ag(+) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridin-2-ylmethyl)pyridin-2-amine ligands in a geometry slightly distorted from linear [N...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238672/ https://www.ncbi.nlm.nih.gov/pubmed/22199563 http://dx.doi.org/10.1107/S1600536811047908 |
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author | Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min |
author_facet | Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min |
author_sort | Moon, Suk-Hee |
collection | PubMed |
description | In the binuclear title compound, [Ag(2)(C(11)H(11)N(3))(2)](CF(3)O(3)S)(2), the complex cation is centrosymmetric, with the unique Ag(+) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridin-2-ylmethyl)pyridin-2-amine ligands in a geometry slightly distorted from linear [N—Ag—N 161.02 (7)°]. This set-up leads to the formation of a 14-membered cyclic dimer. The two pyridine rings coordinated to the Ag(+) cation are tilted by 80.19 (7)° with respect to each other. Intermolecular N—H⋯O hydrogen-bonding interactions between the cyclic dimer and the anion exist. A two-dimensional network parallel to the ac plane is constructed by three weak Ag⋯(O,N) interactions as well as an F⋯F contact of 2.890 (4) Å. |
format | Online Article Text |
id | pubmed-3238672 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386722011-12-23 Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoromethanesulfonate) Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title compound, [Ag(2)(C(11)H(11)N(3))(2)](CF(3)O(3)S)(2), the complex cation is centrosymmetric, with the unique Ag(+) cation coordinated by two pyridine N atoms from two symmetry-related N-(pyridin-2-ylmethyl)pyridin-2-amine ligands in a geometry slightly distorted from linear [N—Ag—N 161.02 (7)°]. This set-up leads to the formation of a 14-membered cyclic dimer. The two pyridine rings coordinated to the Ag(+) cation are tilted by 80.19 (7)° with respect to each other. Intermolecular N—H⋯O hydrogen-bonding interactions between the cyclic dimer and the anion exist. A two-dimensional network parallel to the ac plane is constructed by three weak Ag⋯(O,N) interactions as well as an F⋯F contact of 2.890 (4) Å. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238672/ /pubmed/22199563 http://dx.doi.org/10.1107/S1600536811047908 Text en © Moon et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Moon, Suk-Hee Kim, Tae Ho Park, Ki-Min Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2) N:N′]disilver(I) bis(trifluoromethanesulfonate) |
title | Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2)
N:N′]disilver(I) bis(trifluoromethanesulfonate) |
title_full | Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2)
N:N′]disilver(I) bis(trifluoromethanesulfonate) |
title_fullStr | Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2)
N:N′]disilver(I) bis(trifluoromethanesulfonate) |
title_full_unstemmed | Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2)
N:N′]disilver(I) bis(trifluoromethanesulfonate) |
title_short | Bis[μ-N-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2)
N:N′]disilver(I) bis(trifluoromethanesulfonate) |
title_sort | bis[μ-n-(pyridin-2-ylmethyl)pyridin-2-amine-κ(2)
n:n′]disilver(i) bis(trifluoromethanesulfonate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238672/ https://www.ncbi.nlm.nih.gov/pubmed/22199563 http://dx.doi.org/10.1107/S1600536811047908 |
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