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catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4) O,O′:O′′,O′′′] dihydrate]
In the title compound, {[Cd(C(10)H(8)O(4))(H(2)O)(3)]·2H(2)O}(n), pentagonal–bipyramidally coordinated Cd(II) ions on a twofold rotation axis are linked by tethering 1,4-phenylenediacetate (1,4-phda) ligands into [Cd(1,4-phda)(H(2)O)(3)](n) coordination polymer chains. The chain motifs are oriente...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238673/ https://www.ncbi.nlm.nih.gov/pubmed/22199564 http://dx.doi.org/10.1107/S1600536811047842 |
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author | Uebler, Jacob W. LaDuca, Robert L. |
author_facet | Uebler, Jacob W. LaDuca, Robert L. |
author_sort | Uebler, Jacob W. |
collection | PubMed |
description | In the title compound, {[Cd(C(10)H(8)O(4))(H(2)O)(3)]·2H(2)O}(n), pentagonal–bipyramidally coordinated Cd(II) ions on a twofold rotation axis are linked by tethering 1,4-phenylenediacetate (1,4-phda) ligands into [Cd(1,4-phda)(H(2)O)(3)](n) coordination polymer chains. The chain motifs are oriented parallel to the c-axis direction. Individual chains are connected into a supramolecular network via O—H⋯O hydrogen bonding involving the aqua ligands. |
format | Online Article Text |
id | pubmed-3238673 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386732011-12-23 catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4) O,O′:O′′,O′′′] dihydrate] Uebler, Jacob W. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cd(C(10)H(8)O(4))(H(2)O)(3)]·2H(2)O}(n), pentagonal–bipyramidally coordinated Cd(II) ions on a twofold rotation axis are linked by tethering 1,4-phenylenediacetate (1,4-phda) ligands into [Cd(1,4-phda)(H(2)O)(3)](n) coordination polymer chains. The chain motifs are oriented parallel to the c-axis direction. Individual chains are connected into a supramolecular network via O—H⋯O hydrogen bonding involving the aqua ligands. International Union of Crystallography 2011-11-16 /pmc/articles/PMC3238673/ /pubmed/22199564 http://dx.doi.org/10.1107/S1600536811047842 Text en © Uebler and LaDuca 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Uebler, Jacob W. LaDuca, Robert L. catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4) O,O′:O′′,O′′′] dihydrate] |
title |
catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4)
O,O′:O′′,O′′′] dihydrate] |
title_full |
catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4)
O,O′:O′′,O′′′] dihydrate] |
title_fullStr |
catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4)
O,O′:O′′,O′′′] dihydrate] |
title_full_unstemmed |
catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4)
O,O′:O′′,O′′′] dihydrate] |
title_short |
catena-Poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4)
O,O′:O′′,O′′′] dihydrate] |
title_sort | catena-poly[[(triaquacadmium)-μ-1,4-phenylenediacetato-κ(4)
o,o′:o′′,o′′′] dihydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238673/ https://www.ncbi.nlm.nih.gov/pubmed/22199564 http://dx.doi.org/10.1107/S1600536811047842 |
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