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cis-Aquabromidobis(di-2-pyridylamine-κ(2) N,N′)manganese(II) bromide
In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238689/ https://www.ncbi.nlm.nih.gov/pubmed/22199566 http://dx.doi.org/10.1107/S1600536811048100 |
Sumario: | In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn—N bond trans to the Br atom is slightly longer than the Mn—N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2 (4) and 28.2 (3)°. The complex cations and the Br(−) anions are linked by intermolecular O—H⋯Br and N—H⋯Br hydrogen bonds. Intermolecular π–π interactions are present between the pyridine rings, with a centroid–centroid distance of 3.793 (4) Å. |
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