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cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide

In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238689/
https://www.ncbi.nlm.nih.gov/pubmed/22199566
http://dx.doi.org/10.1107/S1600536811048100
Descripción
Sumario:In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn—N bond trans to the Br atom is slightly longer than the Mn—N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2 (4) and 28.2 (3)°. The complex cations and the Br(−) anions are linked by inter­molecular O—H⋯Br and N—H⋯Br hydrogen bonds. Inter­molecular π–π inter­actions are present between the pyridine rings, with a centroid–centroid distance of 3.793 (4) Å.