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cis-Aquabromidobis(di-2-pyridylamine-κ(2) N,N′)manganese(II) bromide
In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238689/ https://www.ncbi.nlm.nih.gov/pubmed/22199566 http://dx.doi.org/10.1107/S1600536811048100 |
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author | Ha, Kwang |
author_facet | Ha, Kwang |
author_sort | Ha, Kwang |
collection | PubMed |
description | In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn—N bond trans to the Br atom is slightly longer than the Mn—N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2 (4) and 28.2 (3)°. The complex cations and the Br(−) anions are linked by intermolecular O—H⋯Br and N—H⋯Br hydrogen bonds. Intermolecular π–π interactions are present between the pyridine rings, with a centroid–centroid distance of 3.793 (4) Å. |
format | Online Article Text |
id | pubmed-3238689 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386892011-12-23 cis-Aquabromidobis(di-2-pyridylamine-κ(2) N,N′)manganese(II) bromide Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octahedral environment defined by four N atoms of two chelating di-2-pyridylamine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn—N bond trans to the Br atom is slightly longer than the Mn—N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2 (4) and 28.2 (3)°. The complex cations and the Br(−) anions are linked by intermolecular O—H⋯Br and N—H⋯Br hydrogen bonds. Intermolecular π–π interactions are present between the pyridine rings, with a centroid–centroid distance of 3.793 (4) Å. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238689/ /pubmed/22199566 http://dx.doi.org/10.1107/S1600536811048100 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ha, Kwang cis-Aquabromidobis(di-2-pyridylamine-κ(2) N,N′)manganese(II) bromide |
title |
cis-Aquabromidobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) bromide |
title_full |
cis-Aquabromidobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) bromide |
title_fullStr |
cis-Aquabromidobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) bromide |
title_full_unstemmed |
cis-Aquabromidobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) bromide |
title_short |
cis-Aquabromidobis(di-2-pyridylamine-κ(2)
N,N′)manganese(II) bromide |
title_sort | cis-aquabromidobis(di-2-pyridylamine-κ(2)
n,n′)manganese(ii) bromide |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238689/ https://www.ncbi.nlm.nih.gov/pubmed/22199566 http://dx.doi.org/10.1107/S1600536811048100 |
work_keys_str_mv | AT hakwang cisaquabromidobisdi2pyridylaminek2nnmanganeseiibromide |