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cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide

In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the...

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Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238689/
https://www.ncbi.nlm.nih.gov/pubmed/22199566
http://dx.doi.org/10.1107/S1600536811048100
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn—N bond trans to the Br atom is slightly longer than the Mn—N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2 (4) and 28.2 (3)°. The complex cations and the Br(−) anions are linked by inter­molecular O—H⋯Br and N—H⋯Br hydrogen bonds. Inter­molecular π–π inter­actions are present between the pyridine rings, with a centroid–centroid distance of 3.793 (4) Å.
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spelling pubmed-32386892011-12-23 cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octa­hedral environment defined by four N atoms of two chelating di-2-pyridyl­amine (dpa) ligands, one Br(−) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn—N bond trans to the Br atom is slightly longer than the Mn—N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2 (4) and 28.2 (3)°. The complex cations and the Br(−) anions are linked by inter­molecular O—H⋯Br and N—H⋯Br hydrogen bonds. Inter­molecular π–π inter­actions are present between the pyridine rings, with a centroid–centroid distance of 3.793 (4) Å. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238689/ /pubmed/22199566 http://dx.doi.org/10.1107/S1600536811048100 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ha, Kwang
cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide
title cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide
title_full cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide
title_fullStr cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide
title_full_unstemmed cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide
title_short cis-Aqua­bromidobis(di-2-pyridyl­amine-κ(2) N,N′)manganese(II) bromide
title_sort cis-aqua­bromidobis(di-2-pyridyl­amine-κ(2) n,n′)manganese(ii) bromide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238689/
https://www.ncbi.nlm.nih.gov/pubmed/22199566
http://dx.doi.org/10.1107/S1600536811048100
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