cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate

In the mononuclear title complex, [Zn(C(10)H(8)N(2))(2)(C(2)H(6)OS)(2)](C(24)H(20)B)(2)·C(2)H(6)OS, the Zn(II) ion is coordinated by four N atoms of two bidentate 2,2′-bipyridine mol­ecules and by the O atoms of two cis-disposed dimethyl sulfoxide mol­ecules in a distorted octa­hedral geometry. The...

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Autores principales: Tomyn, Stefania, Gumienna-Kontecka, Elżbieta, Usenko, Natalia I., Iskenderov, Turganbay S., Prisyazhnaya, Elena V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238690/
https://www.ncbi.nlm.nih.gov/pubmed/22199567
http://dx.doi.org/10.1107/S1600536811048082
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author Tomyn, Stefania
Gumienna-Kontecka, Elżbieta
Usenko, Natalia I.
Iskenderov, Turganbay S.
Prisyazhnaya, Elena V.
author_facet Tomyn, Stefania
Gumienna-Kontecka, Elżbieta
Usenko, Natalia I.
Iskenderov, Turganbay S.
Prisyazhnaya, Elena V.
author_sort Tomyn, Stefania
collection PubMed
description In the mononuclear title complex, [Zn(C(10)H(8)N(2))(2)(C(2)H(6)OS)(2)](C(24)H(20)B)(2)·C(2)H(6)OS, the Zn(II) ion is coordinated by four N atoms of two bidentate 2,2′-bipyridine mol­ecules and by the O atoms of two cis-disposed dimethyl sulfoxide mol­ecules in a distorted octa­hedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide mol­ecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C—H⋯O hydrogen bonds between the dimethyl sulfoxide solvent mol­ecules and tetra­phenyl­borate anions.
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spelling pubmed-32386902011-12-23 cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate Tomyn, Stefania Gumienna-Kontecka, Elżbieta Usenko, Natalia I. Iskenderov, Turganbay S. Prisyazhnaya, Elena V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Zn(C(10)H(8)N(2))(2)(C(2)H(6)OS)(2)](C(24)H(20)B)(2)·C(2)H(6)OS, the Zn(II) ion is coordinated by four N atoms of two bidentate 2,2′-bipyridine mol­ecules and by the O atoms of two cis-disposed dimethyl sulfoxide mol­ecules in a distorted octa­hedral geometry. The S atom and the methyl groups of one of the coordinated dimethyl sulfoxide mol­ecules are disordered in a 0.509 (2):0.491 (2) ratio. The crystal packing is stabilized by C—H⋯O hydrogen bonds between the dimethyl sulfoxide solvent mol­ecules and tetra­phenyl­borate anions. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238690/ /pubmed/22199567 http://dx.doi.org/10.1107/S1600536811048082 Text en © Tomyn et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tomyn, Stefania
Gumienna-Kontecka, Elżbieta
Usenko, Natalia I.
Iskenderov, Turganbay S.
Prisyazhnaya, Elena V.
cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
title cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
title_full cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
title_fullStr cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
title_full_unstemmed cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
title_short cis-Bis(2,2′-bipyridine-κ(2) N,N′)bis­(dimethyl sulfoxide-κO)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
title_sort cis-bis(2,2′-bipyridine-κ(2) n,n′)bis­(dimethyl sulfoxide-κo)zinc bis­(tetra­phenyl­borate) dimethyl sulfoxide monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238690/
https://www.ncbi.nlm.nih.gov/pubmed/22199567
http://dx.doi.org/10.1107/S1600536811048082
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