Diaqua­bis­(pyridine-2-sulfonato-κ(2) N,O)cobalt(II)

The title complex, [Co(C(5)H(4)NO(3)S)(2)(H(2)O)(2)], lies on a twofold rotation axis that relates the two water mol­ecules and the two pyridine-2-sulfonate ions. The Co(II) atom exists in an slightly distorted octa­hedral environment. The N-donor atoms are cis to each other. In the crystal, adjacen...

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Detalles Bibliográficos
Autores principales: Li, Zong-Sheng, Ng, Seik Weng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238694/
https://www.ncbi.nlm.nih.gov/pubmed/22199571
http://dx.doi.org/10.1107/S1600536811048203
Descripción
Sumario:The title complex, [Co(C(5)H(4)NO(3)S)(2)(H(2)O)(2)], lies on a twofold rotation axis that relates the two water mol­ecules and the two pyridine-2-sulfonate ions. The Co(II) atom exists in an slightly distorted octa­hedral environment. The N-donor atoms are cis to each other. In the crystal, adjacent mol­ecules are linked by O—H⋯O hydrogen bonds into a layer motif extending along (001).

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