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Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium]
In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxylate O atoms from two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One Na(+) cation is coordinated by three carboxy...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238695/ https://www.ncbi.nlm.nih.gov/pubmed/22199572 http://dx.doi.org/10.1107/S1600536811048252 |
Sumario: | In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxylate O atoms from two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One Na(+) cation is coordinated by three carboxylate O atoms and two water molecules and the other is coordinated by five carboxylate O atoms and two water molecules in an irregular geometry. The bis(pyridine-2,6-dicarboxylato)cobalt complex units are connected by Na(+) cations and bridging water molecules into a three-dimensional coordination network. O—H⋯O hydrogen bonds are formed between the water molecules and the carboxylate O atoms. |
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