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Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium]
In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxylate O atoms from two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One Na(+) cation is coordinated by three carboxy...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238695/ https://www.ncbi.nlm.nih.gov/pubmed/22199572 http://dx.doi.org/10.1107/S1600536811048252 |
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author | Boyko, Alexander N. Golenya, Irina A. Izotova, Yulia A. Haukka, Matti Prisyazhnaya, Elena V. |
author_facet | Boyko, Alexander N. Golenya, Irina A. Izotova, Yulia A. Haukka, Matti Prisyazhnaya, Elena V. |
author_sort | Boyko, Alexander N. |
collection | PubMed |
description | In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxylate O atoms from two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One Na(+) cation is coordinated by three carboxylate O atoms and two water molecules and the other is coordinated by five carboxylate O atoms and two water molecules in an irregular geometry. The bis(pyridine-2,6-dicarboxylato)cobalt complex units are connected by Na(+) cations and bridging water molecules into a three-dimensional coordination network. O—H⋯O hydrogen bonds are formed between the water molecules and the carboxylate O atoms. |
format | Online Article Text |
id | pubmed-3238695 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32386952011-12-23 Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] Boyko, Alexander N. Golenya, Irina A. Izotova, Yulia A. Haukka, Matti Prisyazhnaya, Elena V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxylate O atoms from two doubly deprotonated pyridine-2,6-dicarboxylate ligands in a distorted octahedral geometry. One Na(+) cation is coordinated by three carboxylate O atoms and two water molecules and the other is coordinated by five carboxylate O atoms and two water molecules in an irregular geometry. The bis(pyridine-2,6-dicarboxylato)cobalt complex units are connected by Na(+) cations and bridging water molecules into a three-dimensional coordination network. O—H⋯O hydrogen bonds are formed between the water molecules and the carboxylate O atoms. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238695/ /pubmed/22199572 http://dx.doi.org/10.1107/S1600536811048252 Text en © Boyko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Boyko, Alexander N. Golenya, Irina A. Izotova, Yulia A. Haukka, Matti Prisyazhnaya, Elena V. Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] |
title | Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] |
title_full | Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] |
title_fullStr | Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] |
title_full_unstemmed | Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] |
title_short | Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(II)disodium] |
title_sort | poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxylato)-μ(3)-(pyridine-2,6-dicarboxylato)-cobalt(ii)disodium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238695/ https://www.ncbi.nlm.nih.gov/pubmed/22199572 http://dx.doi.org/10.1107/S1600536811048252 |
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