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Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]

In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxyl­ate O atoms from two doubly deprotonated pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. One Na(+) cation is coordinated by three carboxy...

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Autores principales: Boyko, Alexander N., Golenya, Irina A., Izotova, Yulia A., Haukka, Matti, Prisyazhnaya, Elena V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238695/
https://www.ncbi.nlm.nih.gov/pubmed/22199572
http://dx.doi.org/10.1107/S1600536811048252
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author Boyko, Alexander N.
Golenya, Irina A.
Izotova, Yulia A.
Haukka, Matti
Prisyazhnaya, Elena V.
author_facet Boyko, Alexander N.
Golenya, Irina A.
Izotova, Yulia A.
Haukka, Matti
Prisyazhnaya, Elena V.
author_sort Boyko, Alexander N.
collection PubMed
description In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxyl­ate O atoms from two doubly deprotonated pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. One Na(+) cation is coordinated by three carboxyl­ate O atoms and two water mol­ecules and the other is coordinated by five carboxyl­ate O atoms and two water mol­ecules in an irregular geometry. The bis­(pyridine-2,6-dicarboxyl­ato)cobalt complex units are connected by Na(+) cations and bridging water mol­ecules into a three-dimensional coordination network. O—H⋯O hydrogen bonds are formed between the water mol­ecules and the carboxyl­ate O atoms.
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spelling pubmed-32386952011-12-23 Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium] Boyko, Alexander N. Golenya, Irina A. Izotova, Yulia A. Haukka, Matti Prisyazhnaya, Elena V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CoNa(2)(C(7)H(3)NO(4))(2)(H(2)O)(2)](n), the Co(II) atom is coordinated by two pyridine N atoms and four carboxyl­ate O atoms from two doubly deprotonated pyridine-2,6-dicarboxyl­ate ligands in a distorted octa­hedral geometry. One Na(+) cation is coordinated by three carboxyl­ate O atoms and two water mol­ecules and the other is coordinated by five carboxyl­ate O atoms and two water mol­ecules in an irregular geometry. The bis­(pyridine-2,6-dicarboxyl­ato)cobalt complex units are connected by Na(+) cations and bridging water mol­ecules into a three-dimensional coordination network. O—H⋯O hydrogen bonds are formed between the water mol­ecules and the carboxyl­ate O atoms. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238695/ /pubmed/22199572 http://dx.doi.org/10.1107/S1600536811048252 Text en © Boyko et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Boyko, Alexander N.
Golenya, Irina A.
Izotova, Yulia A.
Haukka, Matti
Prisyazhnaya, Elena V.
Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]
title Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]
title_full Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]
title_fullStr Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]
title_full_unstemmed Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]
title_short Poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(II)disodium]
title_sort poly[di-μ(2)-aqua-μ(5)-(pyridine-2,6-dicarboxyl­ato)-μ(3)-(pyridine-2,6-dicarboxyl­ato)-cobalt(ii)disodium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238695/
https://www.ncbi.nlm.nih.gov/pubmed/22199572
http://dx.doi.org/10.1107/S1600536811048252
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