catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]

The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra­hedral...

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Detalles Bibliográficos
Autores principales: Oelkers, Benjamin, Stricker, Marion, Sundermeyer, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238696/
https://www.ncbi.nlm.nih.gov/pubmed/22199573
http://dx.doi.org/10.1107/S1600536811047052
Descripción
Sumario:The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra­hedral coordination sphere. The anionic and neutral ligands lie on different mirror planes (perpendicular to the b and a axis, respectively), while the Cu atom is situated on their inter­section. The asymmetric unit comprises one fourth of the formula unit.

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