catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]

The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra­hedral...

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Detalles Bibliográficos
Autores principales: Oelkers, Benjamin, Stricker, Marion, Sundermeyer, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238696/
https://www.ncbi.nlm.nih.gov/pubmed/22199573
http://dx.doi.org/10.1107/S1600536811047052
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author Oelkers, Benjamin
Stricker, Marion
Sundermeyer, Jörg
author_facet Oelkers, Benjamin
Stricker, Marion
Sundermeyer, Jörg
author_sort Oelkers, Benjamin
collection PubMed
description The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra­hedral coordination sphere. The anionic and neutral ligands lie on different mirror planes (perpendicular to the b and a axis, respectively), while the Cu atom is situated on their inter­section. The asymmetric unit comprises one fourth of the formula unit.
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spelling pubmed-32386962011-12-23 catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido] Oelkers, Benjamin Stricker, Marion Sundermeyer, Jörg Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cu(C(2)N(3))(C(2)H(3)N)(2)](n), features zigzag chains along the a axis that consist of alternating [Cu(MeCN)(2)] and dicyanamide units, the latter acting as bidentate ligands via both terminal N atoms. The Cu atom shows a slightly distorted tetra­hedral coordination sphere. The anionic and neutral ligands lie on different mirror planes (perpendicular to the b and a axis, respectively), while the Cu atom is situated on their inter­section. The asymmetric unit comprises one fourth of the formula unit. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238696/ /pubmed/22199573 http://dx.doi.org/10.1107/S1600536811047052 Text en © Oelkers et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Oelkers, Benjamin
Stricker, Marion
Sundermeyer, Jörg
catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]
title catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]
title_full catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]
title_fullStr catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]
title_full_unstemmed catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]
title_short catena-Poly[[diacetonitrile­copper(I)]-μ-dicyanamido]
title_sort catena-poly[[diacetonitrile­copper(i)]-μ-dicyanamido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238696/
https://www.ncbi.nlm.nih.gov/pubmed/22199573
http://dx.doi.org/10.1107/S1600536811047052
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