Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate

In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol­ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol­ecule. The Rh(III) atom is coordinated by two P atoms in trans positi...

Descripción completa

Detalles Bibliográficos
Autores principales: Muller, Theunis J., Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238697/
https://www.ncbi.nlm.nih.gov/pubmed/22199574
http://dx.doi.org/10.1107/S1600536811047477
Descripción
Sumario:In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol­ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol­ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol­ecule in a distorted octa­hedral geometry. Intra­molecular C—H⋯Cl inter­actions are observed. The uncoordinated acetonitrile mol­ecule is disordered over two sites with occupancies of 0.588 (4) and 0.412 (4).

Ejemplares similares