Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate

In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol­ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol­ecule. The Rh(III) atom is coordinated by two P atoms in trans positi...

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Detalles Bibliográficos
Autores principales: Muller, Theunis J., Visser, Hendrik G., Roodt, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238697/
https://www.ncbi.nlm.nih.gov/pubmed/22199574
http://dx.doi.org/10.1107/S1600536811047477
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author Muller, Theunis J.
Visser, Hendrik G.
Roodt, Andreas
author_facet Muller, Theunis J.
Visser, Hendrik G.
Roodt, Andreas
author_sort Muller, Theunis J.
collection PubMed
description In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol­ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol­ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol­ecule in a distorted octa­hedral geometry. Intra­molecular C—H⋯Cl inter­actions are observed. The uncoordinated acetonitrile mol­ecule is disordered over two sites with occupancies of 0.588 (4) and 0.412 (4).
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spelling pubmed-32386972011-12-23 Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate Muller, Theunis J. Visser, Hendrik G. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [RhCl(3)(CH(3)CN)(C(18)H(21)P)(2)]·2CH(3)CN, the complex mol­ecule lies on a twofold rotation axis that passes through the Rh(III) atom, one Cl atom, and the C and N atoms of the coordinated acetonitrile mol­ecule. The Rh(III) atom is coordinated by two P atoms in trans positions, three Cl atoms and an acetonitrile mol­ecule in a distorted octa­hedral geometry. Intra­molecular C—H⋯Cl inter­actions are observed. The uncoordinated acetonitrile mol­ecule is disordered over two sites with occupancies of 0.588 (4) and 0.412 (4). International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238697/ /pubmed/22199574 http://dx.doi.org/10.1107/S1600536811047477 Text en © Muller et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Muller, Theunis J.
Visser, Hendrik G.
Roodt, Andreas
Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate
title Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate
title_full Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate
title_fullStr Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate
title_full_unstemmed Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate
title_short Acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(III) acetonitrile disolvate
title_sort acetonitrile­trichloridobis(cyclo­hexyl­diphenyl­phosphane)rhodium(iii) acetonitrile disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238697/
https://www.ncbi.nlm.nih.gov/pubmed/22199574
http://dx.doi.org/10.1107/S1600536811047477
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