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A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole
In the title complex, bis{μ-1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole}disilver(I) dinitrate, [Ag(2)(C(10)H(9)N(5))(2)](NO(3))(2), the Ag(I) ion is nearly linearly coordinated [N—Ag—N angle is 155.72 (14)°] by two 1-[(1H-benzimidazole-1-yl)methyl]-1H-1,2,4-triazole (bmt) ligands. In addit...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238699/ https://www.ncbi.nlm.nih.gov/pubmed/22199576 http://dx.doi.org/10.1107/S1600536811048501 |
| _version_ | 1782219038431117312 |
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| author | Wang, Yan-zhi Zhang, Jun Yang, Huai-xia Meng, Xiang-ru |
| author_facet | Wang, Yan-zhi Zhang, Jun Yang, Huai-xia Meng, Xiang-ru |
| author_sort | Wang, Yan-zhi |
| collection | PubMed |
| description | In the title complex, bis{μ-1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole}disilver(I) dinitrate, [Ag(2)(C(10)H(9)N(5))(2)](NO(3))(2), the Ag(I) ion is nearly linearly coordinated [N—Ag—N angle is 155.72 (14)°] by two 1-[(1H-benzimidazole-1-yl)methyl]-1H-1,2,4-triazole (bmt) ligands. In addition, two bmt ligands link two Ag(I) ions, forming a dinuclear unit with an Ag⋯Ag distance of 5.0179 (15) Å. The whole complex is generated by an inversion centre. The dinuclear units and the NO(3) (−) counter-ions are connected by N—H⋯O hydrogen bonds and weak Ag⋯O interactions [2.831 (5), 2.887 (5) and 2.908 (5) Å], leading to a three-dimensional structure. |
| format | Online Article Text |
| id | pubmed-3238699 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32386992011-12-23 A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole Wang, Yan-zhi Zhang, Jun Yang, Huai-xia Meng, Xiang-ru Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, bis{μ-1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole}disilver(I) dinitrate, [Ag(2)(C(10)H(9)N(5))(2)](NO(3))(2), the Ag(I) ion is nearly linearly coordinated [N—Ag—N angle is 155.72 (14)°] by two 1-[(1H-benzimidazole-1-yl)methyl]-1H-1,2,4-triazole (bmt) ligands. In addition, two bmt ligands link two Ag(I) ions, forming a dinuclear unit with an Ag⋯Ag distance of 5.0179 (15) Å. The whole complex is generated by an inversion centre. The dinuclear units and the NO(3) (−) counter-ions are connected by N—H⋯O hydrogen bonds and weak Ag⋯O interactions [2.831 (5), 2.887 (5) and 2.908 (5) Å], leading to a three-dimensional structure. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238699/ /pubmed/22199576 http://dx.doi.org/10.1107/S1600536811048501 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Yan-zhi Zhang, Jun Yang, Huai-xia Meng, Xiang-ru A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole |
| title | A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_full | A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_fullStr | A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_full_unstemmed | A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_short | A new Ag(I) complex based on 1-[(1H-benzimidazol-1-yl)methyl]-1H-1,2,4-triazole |
| title_sort | new ag(i) complex based on 1-[(1h-benzimidazol-1-yl)methyl]-1h-1,2,4-triazole |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238699/ https://www.ncbi.nlm.nih.gov/pubmed/22199576 http://dx.doi.org/10.1107/S1600536811048501 |
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