catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]

The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin­ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl­ate O atom from the pinononate anion, forming a CuN(2)ClO approximat...

Descripción completa

Detalles Bibliográficos
Autores principales: Ma, Shi-ying, Li, Yan-fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238700/
https://www.ncbi.nlm.nih.gov/pubmed/22199577
http://dx.doi.org/10.1107/S1600536811048586
Descripción
Sumario:The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin­ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl­ate O atom from the pinononate anion, forming a CuN(2)ClO approximate square plane. A symmetry-generated pinononate O atom completes a square-based pyramidal geometry for the copper ion. The bridging 2-(3-acetyl-2,2-dimethyl­cyclo­but­yl)acetate anion leads to chains in the crystal propagating in [001]. Adjacent 1,10-phenanthroline rings form a dihedral angle of 39.4 (2)°.

Ejemplares similares