catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]

The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin­ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl­ate O atom from the pinononate anion, forming a CuN(2)ClO approximat...

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Detalles Bibliográficos
Autores principales: Ma, Shi-ying, Li, Yan-fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238700/
https://www.ncbi.nlm.nih.gov/pubmed/22199577
http://dx.doi.org/10.1107/S1600536811048586
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author Ma, Shi-ying
Li, Yan-fei
author_facet Ma, Shi-ying
Li, Yan-fei
author_sort Ma, Shi-ying
collection PubMed
description The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin­ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl­ate O atom from the pinononate anion, forming a CuN(2)ClO approximate square plane. A symmetry-generated pinononate O atom completes a square-based pyramidal geometry for the copper ion. The bridging 2-(3-acetyl-2,2-dimethyl­cyclo­but­yl)acetate anion leads to chains in the crystal propagating in [001]. Adjacent 1,10-phenanthroline rings form a dihedral angle of 39.4 (2)°.
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spelling pubmed-32387002011-12-23 catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}] Ma, Shi-ying Li, Yan-fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cu(C(10)H(15)O(3))Cl(C(12)H(8)N(2))](n), is a one-dimensional coordination polymer. The Cu(II) atom is coordin­ated by a chloride ion, two N atoms from the 1,10-phenanthroline ligand, and a monodentate carboxyl­ate O atom from the pinononate anion, forming a CuN(2)ClO approximate square plane. A symmetry-generated pinononate O atom completes a square-based pyramidal geometry for the copper ion. The bridging 2-(3-acetyl-2,2-dimethyl­cyclo­but­yl)acetate anion leads to chains in the crystal propagating in [001]. Adjacent 1,10-phenanthroline rings form a dihedral angle of 39.4 (2)°. International Union of Crystallography 2011-11-19 /pmc/articles/PMC3238700/ /pubmed/22199577 http://dx.doi.org/10.1107/S1600536811048586 Text en © Ma and Li 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Shi-ying
Li, Yan-fei
catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
title catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
title_full catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
title_fullStr catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
title_full_unstemmed catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
title_short catena-Poly[[chlorido(1,10-phenanthro­line)copper(II)]-μ-{2-[(1S,3S)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
title_sort catena-poly[[chlorido(1,10-phenanthro­line)copper(ii)]-μ-{2-[(1s,3s)-3-acetyl-2,2-dimethyl­cyclo­but­yl]acetato}]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238700/
https://www.ncbi.nlm.nih.gov/pubmed/22199577
http://dx.doi.org/10.1107/S1600536811048586
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AT liyanfei catenapolychlorido110phenanthrolinecopperiim21s3s3acetyl22dimethylcyclobutylacetato

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