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catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]

The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octa­hedral geometry, forming a chain parallel to [010] with the pyrazine carb­oxy­lic acid li...

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Detalles Bibliográficos
Autores principales: Dares, Christopher, Fournier, Rene, Lever, A. B. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238706/
https://www.ncbi.nlm.nih.gov/pubmed/22199583
http://dx.doi.org/10.1107/S1600536811048628
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author Dares, Christopher
Fournier, Rene
Lever, A. B. P.
author_facet Dares, Christopher
Fournier, Rene
Lever, A. B. P.
author_sort Dares, Christopher
collection PubMed
description The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octa­hedral geometry, forming a chain parallel to [010] with the pyrazine carb­oxy­lic acid ligands coordinating on one side in a bidentate fashion through one N and one O atom, and in a monodentate fashion through a N atom, with N atoms trans, and with both ligands lying in the same plane. The bromide atoms are cis to each other, while a water mol­ecule occupies the final octa­hedral coordination site. The chains are linked together though an O—H⋯Br hydrogen bonding network, and are further stabilized by an O—H⋯Br and O—H⋯O hydrogen-bonding framework with the solvent water mol­ecule.
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spelling pubmed-32387062011-12-23 catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate] Dares, Christopher Fournier, Rene Lever, A. B. P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octa­hedral geometry, forming a chain parallel to [010] with the pyrazine carb­oxy­lic acid ligands coordinating on one side in a bidentate fashion through one N and one O atom, and in a monodentate fashion through a N atom, with N atoms trans, and with both ligands lying in the same plane. The bromide atoms are cis to each other, while a water mol­ecule occupies the final octa­hedral coordination site. The chains are linked together though an O—H⋯Br hydrogen bonding network, and are further stabilized by an O—H⋯Br and O—H⋯O hydrogen-bonding framework with the solvent water mol­ecule. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238706/ /pubmed/22199583 http://dx.doi.org/10.1107/S1600536811048628 Text en © Dares et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dares, Christopher
Fournier, Rene
Lever, A. B. P.
catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]
title catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]
title_full catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]
title_fullStr catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]
title_full_unstemmed catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]
title_short catena-Poly[[[cis-aqua­dibromido­cobalt(II)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) N (1),O:N (4)] monohydrate]
title_sort catena-poly[[[cis-aqua­dibromido­cobalt(ii)]-μ-(pyrazine-2-carb­oxy­lic acid)-κ(3) n (1),o:n (4)] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238706/
https://www.ncbi.nlm.nih.gov/pubmed/22199583
http://dx.doi.org/10.1107/S1600536811048628
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