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catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3) N (1),O:N (4)] monohydrate]
The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octahedral geometry, forming a chain parallel to [010] with the pyrazine carboxylic acid li...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238706/ https://www.ncbi.nlm.nih.gov/pubmed/22199583 http://dx.doi.org/10.1107/S1600536811048628 |
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author | Dares, Christopher Fournier, Rene Lever, A. B. P. |
author_facet | Dares, Christopher Fournier, Rene Lever, A. B. P. |
author_sort | Dares, Christopher |
collection | PubMed |
description | The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octahedral geometry, forming a chain parallel to [010] with the pyrazine carboxylic acid ligands coordinating on one side in a bidentate fashion through one N and one O atom, and in a monodentate fashion through a N atom, with N atoms trans, and with both ligands lying in the same plane. The bromide atoms are cis to each other, while a water molecule occupies the final octahedral coordination site. The chains are linked together though an O—H⋯Br hydrogen bonding network, and are further stabilized by an O—H⋯Br and O—H⋯O hydrogen-bonding framework with the solvent water molecule. |
format | Online Article Text |
id | pubmed-3238706 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-32387062011-12-23 catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3) N (1),O:N (4)] monohydrate] Dares, Christopher Fournier, Rene Lever, A. B. P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {[CoBr(2)(C(5)H(4)N(2)O(2))(H(2)O)]·H(2)O}(n), is a one-dimensional coordination polymer which crystallizes as a monohydrate. The asymmetric unit contains one Co(II) atom in a distorted octahedral geometry, forming a chain parallel to [010] with the pyrazine carboxylic acid ligands coordinating on one side in a bidentate fashion through one N and one O atom, and in a monodentate fashion through a N atom, with N atoms trans, and with both ligands lying in the same plane. The bromide atoms are cis to each other, while a water molecule occupies the final octahedral coordination site. The chains are linked together though an O—H⋯Br hydrogen bonding network, and are further stabilized by an O—H⋯Br and O—H⋯O hydrogen-bonding framework with the solvent water molecule. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238706/ /pubmed/22199583 http://dx.doi.org/10.1107/S1600536811048628 Text en © Dares et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Dares, Christopher Fournier, Rene Lever, A. B. P. catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3) N (1),O:N (4)] monohydrate] |
title |
catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3)
N
(1),O:N
(4)] monohydrate] |
title_full |
catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3)
N
(1),O:N
(4)] monohydrate] |
title_fullStr |
catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3)
N
(1),O:N
(4)] monohydrate] |
title_full_unstemmed |
catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3)
N
(1),O:N
(4)] monohydrate] |
title_short |
catena-Poly[[[cis-aquadibromidocobalt(II)]-μ-(pyrazine-2-carboxylic acid)-κ(3)
N
(1),O:N
(4)] monohydrate] |
title_sort | catena-poly[[[cis-aquadibromidocobalt(ii)]-μ-(pyrazine-2-carboxylic acid)-κ(3)
n
(1),o:n
(4)] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238706/ https://www.ncbi.nlm.nih.gov/pubmed/22199583 http://dx.doi.org/10.1107/S1600536811048628 |
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