cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate

The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol­ecules and three dichloro­methane solvent mol­ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238707/
https://www.ncbi.nlm.nih.gov/pubmed/22199584
http://dx.doi.org/10.1107/S1600536811049269
Descripción
Sumario:The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol­ecules and three dichloro­methane solvent mol­ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt—P and Pt—Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P—Pt—P and Cl—Pt—Cl angles of 99.17 (8) and 87.1 (7)°, respectively.

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