cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate

The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol­ecules and three dichloro­methane solvent mol­ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average...

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Detalles Bibliográficos
Autores principales: Davis, Wade L., Meijboom, Reinout
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238707/
https://www.ncbi.nlm.nih.gov/pubmed/22199584
http://dx.doi.org/10.1107/S1600536811049269
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author Davis, Wade L.
Meijboom, Reinout
author_facet Davis, Wade L.
Meijboom, Reinout
author_sort Davis, Wade L.
collection PubMed
description The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol­ecules and three dichloro­methane solvent mol­ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt—P and Pt—Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P—Pt—P and Cl—Pt—Cl angles of 99.17 (8) and 87.1 (7)°, respectively.
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spelling pubmed-32387072011-12-23 cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate Davis, Wade L. Meijboom, Reinout Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol­ecules and three dichloro­methane solvent mol­ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt—P and Pt—Cl bond lengthss of 2.252 (8) and 2.363 (8) Å, respectively, and average P—Pt—P and Cl—Pt—Cl angles of 99.17 (8) and 87.1 (7)°, respectively. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238707/ /pubmed/22199584 http://dx.doi.org/10.1107/S1600536811049269 Text en © Davis and Meijboom 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Davis, Wade L.
Meijboom, Reinout
cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate
title cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate
title_full cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate
title_fullStr cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate
title_full_unstemmed cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate
title_short cis-Bis(benzyl­diphenyl­phosphane-κP)dichloridoplatinum(II) dichloro­methane sesquisolvate
title_sort cis-bis(benzyl­diphenyl­phosphane-κp)dichloridoplatinum(ii) dichloro­methane sesquisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238707/
https://www.ncbi.nlm.nih.gov/pubmed/22199584
http://dx.doi.org/10.1107/S1600536811049269
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