Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)

The title compound, (CH(6)N(3))(5)[H(2)PtV(9)O(28)], containing the nona­vanadoplatinate(IV) polyanion, was obtained by hydro­thermal reaction. The polyanion has approximate C (2v) symmetry. The two Pt-bound μ(2)-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated...

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Detalles Bibliográficos
Autores principales: Joo, Hea-Chung, Park, Ki-Min, Lee, Uk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238708/
https://www.ncbi.nlm.nih.gov/pubmed/22199585
http://dx.doi.org/10.1107/S1600536811049166
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author Joo, Hea-Chung
Park, Ki-Min
Lee, Uk
author_facet Joo, Hea-Chung
Park, Ki-Min
Lee, Uk
author_sort Joo, Hea-Chung
collection PubMed
description The title compound, (CH(6)N(3))(5)[H(2)PtV(9)O(28)], containing the nona­vanadoplatinate(IV) polyanion, was obtained by hydro­thermal reaction. The polyanion has approximate C (2v) symmetry. The two Pt-bound μ(2)-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H(2)PtV(9)O(28)](2)}(10−), held together by each of the two μ(2)-O—H⋯μ(2)-O and μ(2)-O—H⋯μ(3)-O hydrogen bonds. The guanidinium cations are hydrogen bonded with the μ(2)- and terminal O atoms of the polyanion, connecting the polyanions into a three-dimensional network.
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spelling pubmed-32387082011-12-23 Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV) Joo, Hea-Chung Park, Ki-Min Lee, Uk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (CH(6)N(3))(5)[H(2)PtV(9)O(28)], containing the nona­vanadoplatinate(IV) polyanion, was obtained by hydro­thermal reaction. The polyanion has approximate C (2v) symmetry. The two Pt-bound μ(2)-O atoms are protonated in the polyanion. The heteropolyanions form inversion-generated dimers, {[H(2)PtV(9)O(28)](2)}(10−), held together by each of the two μ(2)-O—H⋯μ(2)-O and μ(2)-O—H⋯μ(3)-O hydrogen bonds. The guanidinium cations are hydrogen bonded with the μ(2)- and terminal O atoms of the polyanion, connecting the polyanions into a three-dimensional network. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238708/ /pubmed/22199585 http://dx.doi.org/10.1107/S1600536811049166 Text en © Joo et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Joo, Hea-Chung
Park, Ki-Min
Lee, Uk
Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)
title Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)
title_full Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)
title_fullStr Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)
title_full_unstemmed Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)
title_short Anhydrous penta­guanidinium dihydrogen nona­vanado(IV)platinate(IV)
title_sort anhydrous penta­guanidinium dihydrogen nona­vanado(iv)platinate(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238708/
https://www.ncbi.nlm.nih.gov/pubmed/22199585
http://dx.doi.org/10.1107/S1600536811049166
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