[1,5-Bis(2-meth­oxy­phen­yl)thio­carbazo­nato-κ(2) N (1),S]phenyl­mercury(II)

The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal–phenyl moiety coordinated out of plane with the thio­carbazo­nate ligand by 43.84 (6)°. Important geometrical parameters include Hg—S = 2.3653 (10) Å, Hg—C = 2.058 (4) Å and S—Hg—C = 179.06 (11)°. There is a weak coordination o...

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Detalles Bibliográficos
Autores principales: von Eschwege, Karel, Muller, Fabian, Muller, Alfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238710/
https://www.ncbi.nlm.nih.gov/pubmed/22199587
http://dx.doi.org/10.1107/S1600536811049099
Descripción
Sumario:The title compound, [Hg(C(6)H(5))(C(15)H(15)N(4)O(2)S)], shows the metal–phenyl moiety coordinated out of plane with the thio­carbazo­nate ligand by 43.84 (6)°. Important geometrical parameters include Hg—S = 2.3653 (10) Å, Hg—C = 2.058 (4) Å and S—Hg—C = 179.06 (11)°. There is a weak coordination of an N atom of the ligand to Hg [Hg—N = 2.725 (3) Å]. S⋯Hg inter­actions[3.2928 (10) Å] form chains along [001], stabilizing the crystal structure.

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