catena-Poly[[chloridodimethyl­tin(IV)]-μ-chloro­acetato-κ(2) O:O′]

In the title polymeric coordination compound, [Sn(CH(3))(2)(C(2)H(2)ClO(2))Cl](n), the Sn atom has a distorted trigonal–bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O a...

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Detalles Bibliográficos
Autores principales: Zhang, Shaoliang, Zhang, Junhong, Zhang, Rufen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238711/
https://www.ncbi.nlm.nih.gov/pubmed/22199588
http://dx.doi.org/10.1107/S160053681104918X
Descripción
Sumario:In the title polymeric coordination compound, [Sn(CH(3))(2)(C(2)H(2)ClO(2))Cl](n), the Sn atom has a distorted trigonal–bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction.

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