Cargando…
Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2) P,P′}dichloridoosmium(II)
In the centrosymmetric title compound, [OsCl(2)(C(18)H(40)O(4)P(2))(2)], the Os(II) atom adopts a trans-OsCl(2)P(4) geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the methoxy side chains of the ligand is disordered over two orientations in...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238713/ https://www.ncbi.nlm.nih.gov/pubmed/22199590 http://dx.doi.org/10.1107/S1600536811048926 |
| _version_ | 1782219041635565568 |
|---|---|
| author | Szymczak, Nathaniel K. Zakharov, Lev N. Tyler, David R. |
| author_facet | Szymczak, Nathaniel K. Zakharov, Lev N. Tyler, David R. |
| author_sort | Szymczak, Nathaniel K. |
| collection | PubMed |
| description | In the centrosymmetric title compound, [OsCl(2)(C(18)H(40)O(4)P(2))(2)], the Os(II) atom adopts a trans-OsCl(2)P(4) geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the methoxy side chains of the ligand is disordered over two orientations in a 0.700 (6):0.300 (6) ratio. |
| format | Online Article Text |
| id | pubmed-3238713 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-32387132011-12-23 Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2) P,P′}dichloridoosmium(II) Szymczak, Nathaniel K. Zakharov, Lev N. Tyler, David R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [OsCl(2)(C(18)H(40)O(4)P(2))(2)], the Os(II) atom adopts a trans-OsCl(2)P(4) geometry, arising from its coordination by two chelating diphosphane ligands and two chloride ions. One of the methoxy side chains of the ligand is disordered over two orientations in a 0.700 (6):0.300 (6) ratio. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238713/ /pubmed/22199590 http://dx.doi.org/10.1107/S1600536811048926 Text en © Szymczak et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Szymczak, Nathaniel K. Zakharov, Lev N. Tyler, David R. Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2) P,P′}dichloridoosmium(II) |
| title | Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2)
P,P′}dichloridoosmium(II) |
| title_full | Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2)
P,P′}dichloridoosmium(II) |
| title_fullStr | Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2)
P,P′}dichloridoosmium(II) |
| title_full_unstemmed | Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2)
P,P′}dichloridoosmium(II) |
| title_short | Bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2)
P,P′}dichloridoosmium(II) |
| title_sort | bis{1,2-bis[bis(3-methoxypropyl)phosphanyl]ethane-κ(2)
p,p′}dichloridoosmium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238713/ https://www.ncbi.nlm.nih.gov/pubmed/22199590 http://dx.doi.org/10.1107/S1600536811048926 |
| work_keys_str_mv | AT szymczaknathanielk bis12bisbis3methoxypropylphosphanylethanek2ppdichloridoosmiumii AT zakharovlevn bis12bisbis3methoxypropylphosphanylethanek2ppdichloridoosmiumii AT tylerdavidr bis12bisbis3methoxypropylphosphanylethanek2ppdichloridoosmiumii |