Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate

In the title compound, [Cu(C(7)H(7)N(2)O)Cl(C(7)H(8)N(2)O)]·3H(2)O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0....

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Detalles Bibliográficos
Autores principales: Qiu, Xiumin, Li, Leilei, Li, Dacheng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238715/
https://www.ncbi.nlm.nih.gov/pubmed/22199592
http://dx.doi.org/10.1107/S1600536811049129
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author Qiu, Xiumin
Li, Leilei
Li, Dacheng
author_facet Qiu, Xiumin
Li, Leilei
Li, Dacheng
author_sort Qiu, Xiumin
collection PubMed
description In the title compound, [Cu(C(7)H(7)N(2)O)Cl(C(7)H(8)N(2)O)]·3H(2)O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds. The title compound is the hydrated form of a previously reported structure [Wu & Wu (2008 ▶). Acta Cryst. E64, m828]. There are only slight variations in the mol­ecular geometries of the two compounds.
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spelling pubmed-32387152011-12-23 Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate Qiu, Xiumin Li, Leilei Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(7)N(2)O)Cl(C(7)H(8)N(2)O)]·3H(2)O, the metal ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethanone oxime ligands and by the chloride anion in a distorted square-pyramidal geometry. The distortion parameter is 0.192. The two organic ligands are linked by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules are linked by O—H⋯O and O—H⋯Cl hydrogen bonds. The title compound is the hydrated form of a previously reported structure [Wu & Wu (2008 ▶). Acta Cryst. E64, m828]. There are only slight variations in the mol­ecular geometries of the two compounds. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238715/ /pubmed/22199592 http://dx.doi.org/10.1107/S1600536811049129 Text en © Qiu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qiu, Xiumin
Li, Leilei
Li, Dacheng
Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate
title Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate
title_full Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate
title_fullStr Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate
title_full_unstemmed Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate
title_short Chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) N,N′][1-(2-pyrid­yl)ethanone oxime-κ(2) N,N′]copper(II) trihydrate
title_sort chlorido[1-(pyridin-2-yl)ethanone oximato-κ(2) n,n′][1-(2-pyrid­yl)ethanone oxime-κ(2) n,n′]copper(ii) trihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238715/
https://www.ncbi.nlm.nih.gov/pubmed/22199592
http://dx.doi.org/10.1107/S1600536811049129
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AT lileilei chlorido1pyridin2ylethanoneoximatok2nn12pyridylethanoneoximek2nncopperiitrihydrate
AT lidacheng chlorido1pyridin2ylethanoneoximatok2nn12pyridylethanoneoximek2nncopperiitrihydrate

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