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Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride

In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(−) anions in a distorted square-pyramidal geometry, in which the longest Sb—Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl­anilinium cations link with the co...

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Autor principal: Liu, Ming-Liang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238716/
https://www.ncbi.nlm.nih.gov/pubmed/22199593
http://dx.doi.org/10.1107/S1600536811049087
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author Liu, Ming-Liang
author_facet Liu, Ming-Liang
author_sort Liu, Ming-Liang
collection PubMed
description In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(−) anions in a distorted square-pyramidal geometry, in which the longest Sb—Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl­anilinium cations link with the complex antimonate anions and Cl(−) anions via N—H⋯Cl hydrogen bonds.
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spelling pubmed-32387162011-12-23 Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride Liu, Ming-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(−) anions in a distorted square-pyramidal geometry, in which the longest Sb—Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl­anilinium cations link with the complex antimonate anions and Cl(−) anions via N—H⋯Cl hydrogen bonds. International Union of Crystallography 2011-11-23 /pmc/articles/PMC3238716/ /pubmed/22199593 http://dx.doi.org/10.1107/S1600536811049087 Text en © Ming-Liang Liu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Ming-Liang
Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride
title Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride
title_full Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride
title_fullStr Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride
title_full_unstemmed Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride
title_short Tris(3-methyl­anilinium) penta­chlorido­anti­monate(III) chloride
title_sort tris(3-methyl­anilinium) penta­chlorido­anti­monate(iii) chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238716/
https://www.ncbi.nlm.nih.gov/pubmed/22199593
http://dx.doi.org/10.1107/S1600536811049087
work_keys_str_mv AT liumingliang tris3methylaniliniumpentachloridoantimonateiiichloride