Bis{3-[2-(methyl­sulfon­yl)pyrimidin-4-yl]pyridinium} tetra­chloridocadmium

In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C—H⋯N hydrogen-bonding inter­actions and a weak π–π inter­action is...

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Detalles Bibliográficos
Autores principales: Hu, Dahua, Liu, Xia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3238717/
https://www.ncbi.nlm.nih.gov/pubmed/22199594
http://dx.doi.org/10.1107/S1600536811045995
Descripción
Sumario:In the title compound, (C(10)H(10)N(3)O(2)S)(2)[CdCl(4)], the Cd(II) ion lies on a twofold axis and is coordinated by four chloride anions, with bond distances of 2.4787 (10) and 2.4410 (10) Å. A chain along the c axis is formed by C—H⋯N hydrogen-bonding inter­actions and a weak π–π inter­action is observed between the pyrimidine rings of two adjacent parallel chains [centroid–centroid distance = 3.722 (2) Å]. N—H⋯Cl, CN—H⋯Cl and N—H⋯O interactions also occur.

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